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Crystal structure of bis-{2-[bis-(2-hy-droxy-eth-yl)amino]-ethanol-?(4) O,N,O',O''}cadmium terephthalate.

ABSTRACT: In the title salt, [Cd(C6H15NO3)2](C8H4O4), the Cd(2+) cation is coordinated by six O atoms and two N atoms from two tetra-dentate 2-[bis-(2-hy-droxy-eth-yl)amino]-ethanol ligands, displaying a distorted square-anti-prismatic coordination. The terephthalate dianion does not coordinate to the cation but is connected through O?H-O hydrogen bonds of medium strength to the complex cations, leading to a layered structure extending parallel to (100).

SUBMITTER: Li YP

PROVIDER: S-EPMC4257248 | biostudies-other | 2014 Nov

REPOSITORIES: biostudies-other

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Crystal structure of bis-{2-[bis-(2-hy-droxy-eth-yl)amino]-ethanol-κ(4) O,N,O',O''}cadmium terephthalate.

Li Ya-Ping YP Han Li-Ying LY Ming Julia J Su Guan-Fang GF

Acta crystallographica. Section E, Structure reports online 20141018 Pt 11

In the title salt, [Cd(C6H15NO3)2](C8H4O4), the Cd(2+) cation is coordinated by six O atoms and two N atoms from two tetra-dentate 2-[bis-(2-hy-droxy-eth-yl)amino]-ethanol ligands, displaying a distorted square-anti-prismatic coordination. The terephthalate dianion does not coordinate to the cation but is connected through O⋯H-O hydrogen bonds of medium strength to the complex cations, leading to a layered structure extending parallel to (100). ...[more]

PMID: 25484780

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