Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Photoluminescence and photocatalytic properties of rhombohedral CuGaO2 nanoplates.

ABSTRACT: Rhombohedral phase CuGaO2 nanoplates with a diameter of about 10 μm were synthesized via low temperature hydrothermal method. Room temperature and low temperature photoluminescence of the obtained CuGaO2 nanoplates were characterized. CuGaO2 nanoplates exhibited blue emission at room temperature and free exciton emission were appeared at low temperature. The blue emission is originated from defects such as Cu vacancies, which is the possible origin of p-type conductivity. The appearance of free exciton emission can demonstrate the direct bandgap transition behavior of CuGaO2 nanoplates. The as-prepared p-type CuGaO2 nanoplates were further decorated by n-type ZnO nanoparticles via calcination method to fabricate p-n junction nanocomposites. The nanocomposites exhibited enhanced photocatalytic activity which can be ascribed to the effective separation of photogenerated carriers by the internal electrostatic field in the p-n junction region, and the enhanced light absorption properties resulted from sub-bandgap absorption effect of p-n junction. This work has offered a new insight into the design of p-n junction devices using p-type CuGaO2 nanoplates.

SUBMITTER: Shi L

PROVIDER: S-EPMC4758078 | biostudies-other | 2016

REPOSITORIES: biostudies-other

ACCESS DATA

Json Xml

Similar Datasets

Blue Photoluminescence and Cyan-Colored Afterglow of Undoped SrSO<sub>4</sub> Nanoplates.

Project description:Undoped SrSO4 nanoplates were synthesized via the composite hydroxide-mediated approach. The products were characterized by means of X-ray diffractometry, scanning electron microscopy, X-ray energy-dispersive spectroscopy, X-ray photoelectron spectroscopy, photoluminescence (PL) spectroscopy, electron spin resonance technique, afterglow spectroscopy, and thermoluminescence dosimetry. The steady-state PL spectrum of undoped SrSO4 nanoplates can be deconvoluted into two distinct Gaussian bands centered at 2.97 eV (417.2 nm) and 2.56 eV (484.4 nm), respectively. The nature of the defect emissions is confirmed through the emission-wavelength-dependent PL decays as well as the excitation-wavelength-dependent PL decays. A cyan-colored afterglow from undoped SrSO4 nanoplates can be observed with naked eyes in the dark, and the afterglow spectrum of the undoped SrSO4 nanoplates exhibits a peak at about 492 nm (2.52 eV). The duration of the afterglow is measured to be 16 s. The thermoluminescence glow curve of the undoped SrSO4 nanoplates shows a peak at about 40.1 °C. The trapping parameters are determined with the peak shape method, the calculated value of the trap depth is 0.918 eV, and the frequency factor is 1.2 × 1014 s-1. Using density functional calculations, the band structures and densities of states of oxygen-deficient SrSO4 and strontium-deficient SrSO4 are presented. The mechanisms of the cyan-colored afterglow are discussed for undoped SrSO4, and the oxygen vacancies in SrSO4 are proposed to be the luminescence center of the afterglow.

| S-EPMC8153658 | biostudies-literature

Size-Dependent Photocatalytic Activity of Carbon Dots with Surface-State Determined Photoluminescence.

Project description:Carbon dots (CDs) were synthesized by a microwave-mediated method and separated by size exclusion chromatography into three different size fractions. There was no correlation of the size with photoluminescence (PL) emission wavelength, which shows that the PL mechanism is not quantum-size dependent. UV/vis absorption and diffuse reflectance spectroscopies showed that the light absorption properties as well as the band gap of the CDs changed with the size of the particle. The combination of FTIR and XPS measurements revealed the composition on the surface of each fraction. The three CDs fractions were separately used in the photocatalytic degradation of organic dyes under simulated sunlight irradiation. The catalytic activity of the as-prepared CDs was found to increase as the size of the particles decreased. Complete degradation of both rhodamine B (RhB) and methylene blue (MB) was achieved in 150 min by the 2-nm CDs. The scavenger studies showed that the holes and superoxide radicals are the main species involved in the photocatalytic degradation of the dye by the 2-nm CDs. These CDs displayed high stability in the degradation of organic dyes for multiple cycles. The 2-nm CDs displayed promising photocatalytic degradation of p-nitrophenol (PNP) . These results demonstrate for the first time the application of bare carbon dots in the degradation of environmental contaminants.

| S-EPMC7434043 | biostudies-literature

Controllable Biosynthesis and Properties of Gold Nanoplates Using Yeast Extract.

Project description:AbstractBiosynthesis of gold nanostructures has drawn increasing concerns because of its green and sustainable synthetic process. However, biosynthesis of gold nanoplates is still a challenge because of the expensive source and difficulties of controllable formation of morphology and size. Herein, one-pot biosynthesis of gold nanoplates is proposed, in which cheap yeast was extracted as a green precursor. The morphologies and sizes of the gold nanostructures can be controlled via varying the pH value of the biomedium. In acid condition, gold nanoplates with side length from 1300 ± 200 to 300 ± 100 nm and height from 18 to 15 nm were obtained by increasing the pH value. Whereas, in neutral or basic condition, only gold nanoflowers and nanoparticles were obtained. It was determined that organic molecules, such as succinic acid, lactic acid, malic acid, and glutathione, which are generated in metabolism process, played important role in the reduction of gold ions. Besides, it was found that the gold nanoplates exhibited plasmonic property with prominent dipole infrared resonance in near-infrared region, indicating their potential in surface plasmon-enhanced applications, such as bioimaging and photothermal therapy.Graphical abstract

| S-EPMC6223771 | biostudies-literature

Enhanced Photocatalytic Activity and Photoluminescence of ZnO Nano-Wires Coupled with Aluminum Nanostructures.

Project description:In this study, we fabricated a hybrid plasmonic/semiconductor material by combining the chemical bath deposition of zinc oxide nanowires (ZnONWs) with the physical vapor deposition of aluminum nanostructures (AlNSs) under controlled temperature and atmosphere. The morphological and the optical properties of the ZnONWs/AlNSs hybrid material fabricated at different temperatures (250, 350, and 450 °C) and thicknesses (5, 7, and 9 nm) of Al layers were investigated. By adjusting the deposition and annealing parameters, it was possible to tune the size distribution of the AlNSs. The resonant coupling between the plasmonic AlNSs and ZnONWs leads to an enhanced photoluminescence response. The photocatalytic activity was studied through photodegradation under UV-light irradiation of methylene blue (MB) adsorbed at the surface of ZnO. The MB photodegradation experiment reveals that the ZnONWs covered with 7 nm aluminum film and annealed at 450 °C exhibit the highest degradation efficiency. The comparison between ZnONws and ZnONws/AlNSs shows a photoluminescence enhancement factor of 1.7 and an increase in the kinetics constant of photodegradation with a factor of 4.

| S-EPMC9182769 | biostudies-literature

Indenopyrans - synthesis and photoluminescence properties.

Project description:New indeno[1,2-c]pyran-3-ones bearing different substituents at the pyran moiety were synthesized and their photophysical properties were investigated. In solution all compounds were found to be blue emitters and the trans isomers exhibited significantly higher fluorescence quantum yields (relative to 9,10-diphenylanthracene) as compared to the corresponding cis isomers. The solid-state fluorescence spectra revealed an important red shift of ?max due to intermolecular interactions in the lattice, along with an emission-band broadening, as compared to the solution fluorescence spectra.

| S-EPMC4901902 | biostudies-other

Enhanced Photoluminescence and Photocatalytic Efficiency of La-Doped Bismuth Molybdate: Its Preparation and Characterization.

Project description:Herein, a systematic study of the enhanced physicochemical properties of lanthanide doped (La-doped) bismuth molybdate (Bi2MoO6) is performed. For this purpose, Bi2MoO6 and La-doped Bi2MoO6 were prepared by the sol-gel method. BiCl3, Na2MoO4·2H2O, and LaCl3·7H2O were taken as the main precursors while sodium dodecyl sulfate was used as a surfactant. Both Bi2MoO6 and La-doped Bi2MoO6 were calcined at 650 °C for 2 h. These prepared materials were characterized by spectroscopic techniques such as UV-VIS, FT-IR, XRD, photoluminescence, XPS, along with other techniques such as SEM, TEM, TGA, etc. The investigation of luminescence behavior revealed that the La-doped Bi2MoO6 nanocomposite exhibited much greater luminescence compared to the undoped Bi2MoO6. The photocatalytic behavior of the prepared materials was explored by studying the degradation of methylene blue (MB) at room temperature. The degradation of MB with Bi2MoO6 and La-doped bismuth molybdate were observed to be 68% and 75% @ 45 s, respectively, indicating an enhancement of catalytic performance due to the La doping.

| S-EPMC6981540 | biostudies-literature

CTAB-Assisted Fabrication of Bi₂WO₆ Thin Nanoplates with High Adsorption and Enhanced Visible Light-Driven Photocatalytic Performance.

Project description:Two-dimensional thin Bi₂WO₆ nanoplates have been fabricated using a cetyltrimethylammonium bromide (CTAB)-assisted hydrothermal method. We investigated the proposed formation mechanism based on the crystalline structures of the thin Bi₂WO₆ nanoplates. The high adsorption ability and excellent visible-light driven photocatalytic activities of the Bi₂WO₆ nanoplates were illustrated, in view of exposed (001) facets of nanoplates possessing faster separation of photo-generated charge carriers and increased catalytically active sites. Such a cost-effective way to obtain Bi₂WO₆ nanoplates offers new possibilities for the design of adsorptive semiconductor photocatalysts with strengthened photocatalytic activities.

| S-EPMC6153929 | biostudies-literature

Visible-Light-Driven Ag-Doped BiOBr Nanoplates with an Enhanced Photocatalytic Performance for the Degradation of Bisphenol A.

Project description:Based on the low utilization rate of visible light and the high-charge carriers-recombination efficiency of bismuth oxybromide (BiOBr), in this work, noble metal Ag was used to modify BiOBr, and Ag-doped BiOBr nanoplates (Ag-BiOBr) were obtained through a one-step hydrothermal method. Compared with BiOBr, the absorption edge of Ag-BiOBr showed a redshift from 453 nm to 510 nm, and the absorption efficiency of visible light was, obviously, improved. Bisphenol A (BPA) was chosen as the target pollutant, to evaluate the photocatalytic performance of the samples. Ag0.1-BiOBr showed the highest degradation efficiency. The intrinsic photocatalytic activity of Ag0.1-BiOBr, under visible light, was approximately twice as high as that of BiOBr. In this way, a new visible-light-driven photocatalyst was proposed, to fight against organic pollution, which provides a promising strategy for water and wastewater treatment.

| S-EPMC9182274 | biostudies-literature

Photocatalytic Properties of Porous Silicon Nanowires.

Project description:Porous silicon nanowires are synthesized through metal assisted wet-chemical etch of highly-doped silicon wafer. The resulted porous silicon nanowires exhibit a large surface area of 337 m(2)·g(-1) and a wide spectrum absorption across the entire ultraviolet, visible and near infrared regime. We further demonstrate that platinum nanoparticles can be loaded onto the surface of the porous silicon nanowires with controlled density. These combined advancements make the porous silicon nanowires an interesting material for photocatalytic applications. We show that the porous silicon nanowires and platinum nanoparticle loaded porous silicon nanowires can be used as effective photocatalysts for photocatalytic degradation of organic dyes and toxic pollutants under visible irradiation, and thus are of significant interest for organic waste treatment and environmental remediation.

| S-EPMC3242411 | biostudies-literature

Ionic permeability and mechanical properties of DNA origami nanoplates on solid-state nanopores.

Project description:While DNA origami is a popular and versatile platform, its structural properties are still poorly understood. In this study we use solid-state nanopores to investigate the ionic permeability and mechanical properties of DNA origami nanoplates. DNA origami nanoplates of various designs are docked onto solid-state nanopores where we subsequently measure their ionic conductance. The ionic permeability is found to be high for all origami nanoplates. We observe the conductance of docked nanoplates, relative to the bare nanopore conductance, to increase as a function of pore diameter, as well as to increase upon lowering the ionic strength. The honeycomb lattice nanoplate is found to have slightly better overall performance over other plate designs. After docking, we often observe spontaneous discrete jumps in the current, a process which can be attributed to mechanical buckling. All nanoplates show a nonlinear current-voltage dependence with a lower conductance at higher applied voltages, which we attribute to a physical bending deformation of the nanoplates under the applied force. At sufficiently high voltage (force), the nanoplates are strongly deformed and can be pulled through the nanopore. These data show that DNA origami nanoplates are typically very permeable to ions and exhibit a number of unexpected mechanical properties, which are interesting in their own right, but also need to be considered in the future design of DNA origami nanostructures.

| S-EPMC4151284 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data