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Crystal structure of 2-[chloro-(4-meth-oxy-phen-yl)meth-yl]-2-(4-meth-oxy-phen-yl)-5,5-di-methyl-cyclo-hexane-1,3-dione.

ABSTRACT: In the title compound, C23H25ClO4, the cyclo-hexane ring adopts a chair conformation with the 4-meth-oxy-phenyl substituent in an axial position and the chloro-(4-meth-oxy-phen-yl)methyl substituent in an equatorial position. The packing features inversion dimers formed by pairs of C-H?O contacts and strands along [100] and [010] established by further C-H?O and C-H?Cl contacts, respectively.

SUBMITTER: Chelli S

PROVIDER: S-EPMC4778832 | biostudies-other | 2016 Mar

REPOSITORIES: biostudies-other

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Crystal structure of 2-[chloro-(4-meth-oxy-phen-yl)meth-yl]-2-(4-meth-oxy-phen-yl)-5,5-di-methyl-cyclo-hexane-1,3-dione.

Chelli Saloua S Troshin Konstantin K Lakhdar Sami S Mayr Herbert H Mayer Peter P

Acta crystallographica. Section E, Crystallographic communications 20160206 Pt 3

In the title compound, C23H25ClO4, the cyclo-hexane ring adopts a chair conformation with the 4-meth-oxy-phenyl substituent in an axial position and the chloro-(4-meth-oxy-phen-yl)methyl substituent in an equatorial position. The packing features inversion dimers formed by pairs of C-H⋯O contacts and strands along [100] and [010] established by further C-H⋯O and C-H⋯Cl contacts, respectively. ...[more]

PMID: 27006792

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