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Novel strip-cast Mg/Al clad sheets with excellent tensile and interfacial bonding properties.

ABSTRACT: In order to broaden industrial applications of Mg alloys, as lightest-weight metal alloys in practical uses, many efforts have been dedicated to manufacture various clad sheets which can complement inherent shortcomings of Mg alloys. Here, we present a new fabrication method of Mg/Al clad sheets by bonding thin Al alloy sheet on to Mg alloy melt during strip casting. In the as-strip-cast Mg/Al clad sheet, homogeneously distributed equi-axed dendrites existed in the Mg alloy side, and two types of thin reaction layers, i.e., γ (Mg17Al12) and β (Mg2Al3) phases, were formed along the Mg/Al interface. After post-treatments (homogenization, warm rolling, and annealing), the interfacial layers were deformed in a sawtooth shape by forming deformation bands in the Mg alloy and interfacial layers, which favorably led to dramatic improvement in tensile and interfacial bonding properties. This work presents new applications to multi-functional lightweight alloy sheets requiring excellent formability, surface quality, and corrosion resistance as well as tensile and interfacial bonding properties.

SUBMITTER: Kim JS

PROVIDER: S-EPMC4888122 | biostudies-other | 2016

REPOSITORIES: biostudies-other

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Novel twin-roll-cast Ti/Al clad sheets with excellent tensile properties.

Project description:Pure Ti or Ti alloys are recently spot-lighted in construction industries because they have excellent resistance to corrosions, chemicals, and climates as well as various coloring characteristics, but their wide applications are postponed by their expensiveness and poor formability. We present a new fabrication process of Ti/Al clad sheets by bonding a thin Ti sheet on to a 5052 Al alloy melt during vertical-twin-roll casting. This process has merits of reduced production costs as well as improved tensile properties. In the as-twin-roll-cast clad sheet, the homogeneously cast microstructure existed in the Al alloy substrate side, while the Ti/Al interface did not contain any reaction products, pores, cracks, or lateral delamination, which indicated the successful twin-roll casting. When this sheet was annealed at 350 °C~600 °C, the metallurgical bonding was expanded by interfacial diffusion, thereby leading to improvement in tensile properties over those calculated by a rule of mixtures. The ductility was also improved over that of 5052-O Al alloy (25%) or pure Ti (25%) by synergic effect of homogeneous deformation due to excellent Ti/Al bonding. This work provides new applications of Ti/Al clad sheets to lightweight-alloy clad sheets requiring excellent formability and corrosion resistance as well as alloy cost saving.

| S-EPMC5556021 | biostudies-other

The Behaviour of Bifilm Defects in Cast Al-7Si-Mg Alloy.

Project description:Double oxide films (bifilms) are significant defects in the casting of light alloys, and have been shown to decrease tensile and fatigue properties, and also to increase their scatter, making casting properties unreproducible and unreliable. A bifilm consists of doubled-over oxide films containing a gas-filled crevice and is formed due to surface turbulence of the liquid metal during handling and/or pouring. Previous studies has shown that the nature of oxide film defects may change with time, as the atmosphere inside the bifilm could be consumed by reaction with the surrounding melt, which may enhance the mechanical properties of Al alloy castings. As a proxy for a bifilm, an air bubble was trapped within an Al-7wt.%Si-0.3wt.%Mg (2L99) alloy melt, subjected to stirring. The effect of different parameters such as the holding time, stirring velocity and melt temperature on the change in gas composition of the bubble was investigated, using a design of experiments (DoE) approach. Also, the solid species inside the bubbles solidified in the melt were examined using SEM. The results suggested that both oxygen and nitrogen inside the bifilm would be consumed by reaction with the surrounding melt producing MgAl2O4 and AlN, respectively. Also, hydrogen was suggested to consistently diffuse into the defect. The reaction rates and the rate of H diffusion were shown to increase upon increasing the holding time and temperature, and stirring velocity. Such significant effect of the process parameters studied on the gaseous content of the bubble suggesting that a careful control of such parameters might lead to the deactivation of bifilm defects, or at least elimination of their deteriorous effect in light alloy castings.

| S-EPMC4987044 | biostudies-literature

Formation of strength platform in cast Al-Si-Mg-Cu alloys.

Project description:Over the past several decades, it was generally believed that the strength of the industrially widely used cast Al-Si-Mg-Cu alloys enhanced monotonously with increasing Cu content. However, in this study using cast Al9Si0.5MgxCu (x = 0,0.2,0.4,0.6,0.85,1.0,1.25, in wt.%) alloys under T6 heat-treated condition, it was found that the hardness and yield strength of the heat-treated alloys showed a platform in the composition range from 0.4 wt.% to 0.85 wt.% Cu, while still increased with increasing Cu content before and after the platform. With increasing Cu content, the β-Mg2Si intermetallic phase decreased and disappeared at 0.85 wt.% Cu, while the Q-Al5Cu2Mg8Si6 and θ-Al2Cu intermetallic phases increased in the as-cast alloys. After heat treatment, the micron-scale intermetallic phases were dissolved into the Al matrix and precipitated as the nanoscale β″, Q' and θ' strengthening phases. With increasing Cu content, the β″ precipitate decreased and vanished at 0.85 wt.% Cu, while the Q' and θ' precipitates increased in the heat-treated alloys. The trade-off of the phases induces the platform in the strength of the heat-treated alloys, and further increase of the Cu content in this undetected trapped platform range is not favorited industrially as it only decreases ductility.

| S-EPMC6610148 | biostudies-literature

Annealing Effects in Twin-Roll Cast AA8006 Aluminium Sheets Processed by Accumulative Roll-Bonding.

Project description:Ultrafine grained sheets were prepared from a twin-roll cast AA8006 aluminium alloy using accumulative roll-bonding process at room temperature. The evolution of microstructure of sheets after three accumulative roll-bonding passes during isochronal annealing with a constant step of 20 °C/20 min was studied by light and electron microscopy. The influence of the resulting microstructure on mechanical properties was monitored by microhardness measurements. The microhardness increases when the material is annealed up to 160 °C. Above this temperature a fast drop of microhardness occurs followed by a negligible variation at annealing temperatures exceeding 300 °C. In order to map continuously the microstructure changes during annealing, the in situ TEM experiments in the heating stage were performed as a supplement to post-mortem TEM observations.

| S-EPMC5456430 | biostudies-other

Fabrication of Al/Mg/Al Composites via Accumulative Roll Bonding and Their Mechanical Properties.

Project description:Al(1060)/Mg(AZ31)/Al(1060) multilayered composite was successfully produced using an accumulative roll bonding (ARB) process for up to four cycles at an elevated temperature (400 °C). The microstructure evolution of the composites and the bonding characteristics at the interfaces between Al and Mg layers with increasing ARB cycles were characterized through optical microscopy, field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). It was found that the grains of Al and Mg layers were significantly refined and Al₃Mg₂ and Al12 Mg17 intermetallic compound layers formed at the Al/Mg bonding interfaces. The strength increased gradually and the ultimate tensile strength (UTS) reached a maximum value of about 240 MPa at the third pass. Furthermore, the strengthening mechanism of the composite was analyzed based on the fracture morphologies.

| S-EPMC5457262 | biostudies-other

Unsupported Mg-Alkene Bonding.

Project description:The first intermolecular early main group metal-alkene complexes were isolated. This was enabled by using highly Lewis acidic Mg centers in the Lewis base-free cations (Me BDI)Mg+ and (tBu BDI)Mg+ with B(C6 F5 )4 - counterions (Me BDI=CH[C(CH3 )N(DIPP)]2 , tBu BDI=CH[C(tBu)N(DIPP)]2 , DIPP=2,6-diisopropylphenyl). Coordination complexes with various mono- and bis-alkene ligands, typically used in transition metal chemistry, were structurally characterized for 1,3-divinyltetramethyldisiloxane, 1,5-cyclooctadiene, cyclooctene, 1,3,5-cycloheptatriene, 2,3-dimethylbuta-1,3-diene, and 2-ethyl-1-butene. In all cases, asymmetric Mg-alkene bonding with a short and a long Mg-C bond is observed. This asymmetry is most extreme for Mg-(H2 C=CEt2 ) bonding. In bromobenzene solution, the Mg-alkene complexes are either dissociated or in a dissociation equilibrium. A DFT study and AIM analysis showed that the C=C bonds hardly change on coordination and there is very little alkene→Mg electron transfer. The Mg-alkene bonds are mainly electrostatic and should be described as Mg2+ ion-induced dipole interactions.

| S-EPMC7898539 | biostudies-literature

Effect of Rolling Route on Microstructure and Tensile Properties of Twin-Roll Casting AZ31 Mg Alloy Sheets.

Project description:Twin-roll casting AZ31 Mg alloy sheets have been fabricated by normal unidirectional-rolling, head-to-tail rolling, and clock-rolling, respectively. It has been demonstrated that head-to-tail rolling is the most effective to refine the microstructure and weaken the basal texture among the three rolling routes. Excellent integrated tensile properties can be obtained by the head-to-tail rolling. The yield strength, ultimate tensile strength, and plastic elongation are 196 MPa, 301 MPa, and 28.9%, respectively. The strength can benefit from the fine grains (average value of 4.0 μm) of the AZ31 alloy processed by the head-to-tail rolling route, while the excellent plastic elongation is achieved owing to the weakened basal texture besides the fine grains. Results obtained here can be used as a basis for further study of some simple rolling methods, which is critical to the development of Mg alloys with high strength and plasticity.

| S-EPMC5456789 | biostudies-other

Ambiphilic Al-Cu Bonding.

Project description:Copper-alumanyl complexes, [LCu-Al(SiNDipp )], where L=carbene=NHCiPr (N,N'-diisopropyl-4,5-dimethyl-2-ylidene) and Me2 CAAC (1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethyl-pyrrolidin-2-ylidene) and featuring unsupported Al-Cu bonds, have been prepared. Divergent reactivity observed with carbodiimides and CO2 implies an ambiphilicity in the Cu-Al interaction that is dependent on the identity of the carbene co-ligand.

| S-EPMC8252794 | biostudies-literature

Porosity Defect Remodeling and Tensile Analysis of Cast Steel.

Project description:Tensile properties on ASTM A216 WCB cast steel with centerline porosity defect were studied with radiographic mapping and finite element remodeling technique. Non-linear elastic and plastic behaviors dependent on porosity were mathematically described by relevant equation sets. According to the ASTM E8 tensile test standard, matrix and defect specimens were machined into two categories by two types of height. After applying radiographic inspection, defect morphologies were mapped to the mid-sections of the finite element models and the porosity fraction fields had been generated with interpolation method. ABAQUS input parameters were confirmed by trial simulations to the matrix specimen and comparison with experimental outcomes. Fine agreements of the result curves between simulations and experiments could be observed, and predicted positions of the tensile fracture were found to be in accordance with the tests. Chord modulus was used to obtain the equivalent elastic stiffness because of the non-linear features. The results showed that elongation was the most influenced term to the defect cast steel, compared with elastic stiffness and yield stress. Additional visual explanations on the tensile fracture caused by void propagation were also given by the result contours at different mechanical stages, including distributions of Mises stress and plastic strain.

| S-EPMC5456474 | biostudies-other

Interfacial chemical bonding-mediated ionic resistive switching.

Project description:In this paper, we present a unique resistive switching (RS) mechanism study of Pt/TiO2/Pt cell, one of the most widely studied RS system, by focusing on the role of interfacial bonding at the active TiO2-Pt interface, as opposed to a physico-chemical change within the RS film. This study was enabled by the use of a non-conventional scanning probe-based setup. The nanoscale cell is formed by bringing a Pt/TiO2-coated atomic force microscope tip into contact with a flat substrate coated with Pt. The study reveals that electrical resistance and interfacial bonding status are highly coupled together. An oxygen-mediated chemical bonding at the active interface between TiO2 and Pt is a necessary condition for a non-polar low-resistance state, and a reset switching process disconnects the chemical bonding. Bipolar switching mode did not involve the chemical bonding. The nature of chemical bonding at the TiO2-metal interface is further studied by density functional theory calculations.

| S-EPMC5430901 | biostudies-literature

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