Ontology highlight
ABSTRACT:
SUBMITTER: Setifi F
PROVIDER: S-EPMC4910331 | biostudies-other | 2016 Apr
REPOSITORIES: biostudies-other
Acta crystallographica. Section E, Crystallographic communications 20160308 Pt 4
The search for new mol-ecular materials with inter-esting magnetic properties, using the pseudohalide azide ion and di-2-pyridyl-amine (dpa, C10H9N3) as a chelating ligand, led to the synthesis and structure determination of the title compound, [Co(N3)2(dpa)2]2SO4·2H2O. The crystal structure comprises discrete [Co(dpa)2(N3)2](+) cations, sulfate anions, as well as H2O solvent mol-ecules. The Co(III) cations display a slightly distorted octa-hedral coordination sphere defined by two N atoms from ...[more]