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Crystal structure of bis-(isonicotinamide-?N (1))bis-(thio-cyanato-?N)zinc.

ABSTRACT: The asymmetric unit of the title complex, [Zn(SCN)2(C6H6N2O)2], consists of one Zn(2+) cation located on a twofold rotation axis, as well as of one thio-cyanate anion and one neutral isonicotinamide ligand, both occupying general positions. The Zn(2+) cation is tetra-hedrally coordinated into a discrete complex by the N atoms of two symmetry-related thio-cyanate anions and by the pyridine N atoms of two isonicotinamide ligands. The complexes are linked by inter-molecular C-H?O and N-H?O, and weak inter-molecular N-H?S hydrogen-bonding inter-actions into a three-dimensional network.

SUBMITTER: Neumann T

PROVIDER: S-EPMC4992907 | biostudies-other | 2016 Jul

REPOSITORIES: biostudies-other

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Crystal structure of bis-(isonicotinamide-κN (1))bis-(thio-cyanato-κN)zinc.

Neumann Tristan T Jess Inke I Näther Christian C

Acta crystallographica. Section E, Crystallographic communications 20160610 Pt 7

The asymmetric unit of the title complex, [Zn(SCN)2(C6H6N2O)2], consists of one Zn(2+) cation located on a twofold rotation axis, as well as of one thio-cyanate anion and one neutral isonicotinamide ligand, both occupying general positions. The Zn(2+) cation is tetra-hedrally coordinated into a discrete complex by the N atoms of two symmetry-related thio-cyanate anions and by the pyridine N atoms of two isonicotinamide ligands. The complexes are linked by inter-molecular C-H⋯O and N-H⋯O, and wea ...[more]

PMID: 27555932

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