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Ceo₂ Based Catalysts for the Treatment of Propylene in Motorcycle's Exhaust Gases.

ABSTRACT: In this work, the catalytic activities of several single metallic oxides were studied for the treatment of propylene, a component in motorcycles' exhaust gases, under oxygen deficient conditions. Amongst them, CeO₂ is one of the materials that exhibit the highest activity for the oxidation of C₃H₆. Therefore, several mixtures of CeO₂ with other oxides (SnO₂, ZrO₂, Co₃O₄) were tested to investigate the changes in catalytic activity (both propylene conversion and CO₂ selectivity). Ce0.9Zr0.1O₂, Ce0.8Zr0.2O₂ solid solutions and the mixtures of CeO₂ and Co₃O₄ was shown to exhibit the highest propylene conversion and CO₂ selectivity. They also exhibited good activities when tested under oxygen sufficient and excess conditions and with the presence of co-existing gases (CO, H₂O).

SUBMITTER: Pham PTM

PROVIDER: S-EPMC5512641 | biostudies-other | 2014 Nov

REPOSITORIES: biostudies-other

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Project description:Algae provide a rich source of proteins, lipids, vitamins, and minerals, making them valuable feed ingredients in animal nutrition. Beyond their nutritional benefits, algae have been recognized for their potential to mitigate the negative environmental impacts of poultry production. Poultry production is crucial for the global food supply but contributes to environmental concerns, particularly in terms of ammonia and carbon dioxide gas emissions. This study emphasizes the importance of reducing greenhouse gas and ammonia production in poultry operations by utilizing algae species suitable for animal consumption, highlighting the need for sustainable feed sources. This study investigated the effects of poultry exhaust air and culture conditions on the amino acid profiles of three microalgae species, namely, Scenedesmus sp. (AQUAMEB-60), Ankistrodesmus sp. (AQUAMEB-33), and Synechococcaceae (AQUAMEB 32). The experiments were conducted in a commercial broiler farm in Bursa, Turkey, focusing on reducing pollutant gas emissions and utilizing poultry exhaust air in algae cultivation. The highest protein content of 50.4% was observed in the biomass of Synechococcaceae with BBM and DI water. Scenedesmus sp. had the highest carbohydrate content of 33.4% cultivated with DI water. The algae biomass produced from Synechococcaceae growth with DI water was found to have the highest content of essential and nonessential amino acids, except for glutamic acid and glycine. The arsenic, cadmium, and mercury content showed variations within the following respective ranges: 1.076-3.500 mg/kg, 0.0127-0.1210 mg/kg, and 0.1330-0.0124 mg/kg. The overall operating costs for producing 1.0 g L-1 d-1 of dry algal biomass with the existing PBR system were $0.12-0.35 L-1 d-1, $0.10-0.26 L-1 d-1, and $0.11-0.24 L-1 d-1 for Scenedesmus sp., Ankistrodesmus sp., and Synechococcaceae, respectively. The operating cost of producing 1.0 g L-1 d-1 of protein was in the range of $0.25-0.88 L-1 d-1 for the three algae species. The results provide insights into the potential of algae as a sustainable feed ingredient in animal diets, emphasizing both environmental and economic considerations. The results demonstrated a considerable reduction in the production costs of dry biomass and protein when utilizing poultry house exhaust air, highlighting the economic viability and nutritional benefits of this cultivation method.

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Ceo₂ Based Catalysts for the Treatment of Propylene in Motorcycle's Exhaust Gases.

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