Unknown

Dataset Information

0

Enantiomerically enriched tris(boronates): readily accessible conjunctive reagents for asymmetric synthesis.

ABSTRACT: The catalytic enantioselective diboration of vinyl boronate esters furnishes chiral tris(boronates) in a selective fashion. Subsequent deborylative alkylation occurs in a diastereoselective fashion, both for intermolecular and intramolecular processes.

SUBMITTER: Coombs JR 

PROVIDER: S-EPMC5539535 | biostudies-other | 2014 Nov

REPOSITORIES: biostudies-other

Json Xml
altmetric image

Publications

Enantiomerically enriched tris(boronates): readily accessible conjunctive reagents for asymmetric synthesis.

Coombs John R JR   Zhang Liang L   Morken James P JP  

Journal of the American Chemical Society 20141111 46

The catalytic enantioselective diboration of vinyl boronate esters furnishes chiral tris(boronates) in a selective fashion. Subsequent deborylative alkylation occurs in a diastereoselective fashion, both for intermolecular and intramolecular processes. ...[more]

Similar Datasets

Unknown Asymmetric NHC-catalyzed synthesis of ?-fluoroamides from readily accessible ?-fluoroenals.
| S-EPMC4205762 | biostudies-literature
Unknown Synthesis of enantiomerically enriched imidazolidin-2-ones through asymmetric palladium-catalyzed alkene carboamination reactions.
| S-EPMC3517004 | biostudies-literature
Unknown Asymmetric palladium-catalyzed carboamination reactions for the synthesis of enantiomerically enriched 2-(arylmethyl)- and 2-(alkenylmethyl)pyrrolidines.
| S-EPMC2932842 | biostudies-literature
Unknown Readily accessible multifunctional fluorous emulsions.
| S-EPMC6020120 | biostudies-literature
Unknown Highly efficient synthesis of enantiomerically enriched 2-hydroxymethylaziridines by enzymatic desymmetrization.
| S-EPMC2529399 | biostudies-literature
Unknown Intramolecular alkene carboamination reactions for the synthesis of enantiomerically enriched tropane derivatives.
| S-EPMC3103612 | biostudies-literature
Unknown Enantiomerically enriched, polycrystalline molecular sieves.
| S-EPMC5441830 | biostudies-other
Unknown Readily Accessible Ambiphilic Cyclopentadienes for Bioorthogonal Labeling.
| S-EPMC6314806 | biostudies-literature
Unknown Preparation of Enantiomerically Pure Perfluorobutanesulfinamide and Its Application to the Asymmetric Synthesis of ?-Amino Acids.
| S-EPMC4761297 | biostudies-literature
Unknown Functionally Diverse Nylon-3 Copolymers from Readily Accessible ?-Lactams.
| S-EPMC3551626 | biostudies-literature