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Oxidative [1,2]-Brook Rearrangements Exploiting Single-Electron Transfer: Photoredox-Catalyzed Alkylations and Arylations.


ABSTRACT: Oxidative [1,2]-Brook rearrangements via hypervalent silicon intermediates induced by photoredox-catalyzed single-electron transfer have been achieved, permitting the formation of reactive radical species that can engage in alkylations and arylations.

SUBMITTER: Deng Y 

PROVIDER: S-EPMC5575796 | biostudies-other | 2017 Jul

REPOSITORIES: biostudies-other

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Oxidative [1,2]-Brook Rearrangements Exploiting Single-Electron Transfer: Photoredox-Catalyzed Alkylations and Arylations.

Deng Yifan Y   Liu Qi Q   Smith Amos B AB  

Journal of the American Chemical Society 20170710 28


Oxidative [1,2]-Brook rearrangements via hypervalent silicon intermediates induced by photoredox-catalyzed single-electron transfer have been achieved, permitting the formation of reactive radical species that can engage in alkylations and arylations. ...[more]

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