Ontology highlight
ABSTRACT:
SUBMITTER: Zakharova AN
PROVIDER: S-EPMC6017268 | biostudies-other | 2018 Feb
REPOSITORIES: biostudies-other
Zakharova Alexandra N AN Awan Shahid I SI Nami Faranak F Gotfredsen Charlotte H CH Madsen Robert R Clausen Mads H MH
Molecules (Basel, Switzerland) 20180203 2
The synthesis of two protected tetrasaccharide pentenyl glycosides with diarabinan and digalactan branching related to the pectic polysaccharide rhamnogalacturonan I is reported. The strategy relies on the coupling of <i>N</i>-phenyl trifluoroacetimidate disaccharide donors to a common rhamnosyl acceptor. The resulting trisaccharide thioglycosides were finally coupled to an <i>n</i>-pentenyl galactoside acceptor to access the two protected branched tetrasaccharides. ...[more]