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Organometallic-Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and CuI Ions.

ABSTRACT: A multicomponent approach of the P n ligand complex [Cp*Fe(?5-P5)] (1: Cp* = ?5-C5Me5) with the ditopic organic linkers 4,4'-bipyridine (2) or trans-1,2-di(pyridine-4-yl)ethene (3) in the presence of CuI salts of the anions [BF4]- and [PF6]- or the coordinating anion Br-, leads to the formation of four novel organometallic-organic hybrid polymers: the cationic 1D polymeric compounds [Cu4{Cp*Fe(µ3,?5:1:1-P5)}2(µ,?1:1-C10H8N2)4(CH3CN)4] n [BF4]4n (4) and [Cu4{Cp*Fe(µ3,?5:1:1-P5)}2(µ,?1:1-C10H8N2)4(CH3CN)4] n [PF6]4n (5) as well as the unique neutral threefold 2D ? 2D interpenetrated networks [Cu2Cl2{Cp*Fe(µ3,?5:1:1-P5)}(µ,?1:1-C12H10N2)] n (6) and [Cu2Br2{Cp*Fe(µ3,?5:1:1-P5)}(µ,?1:1-C10H8N2)] n (7).

SUBMITTER: Moussa ME

PROVIDER: S-EPMC6049892 | biostudies-other | 2018 Jun

REPOSITORIES: biostudies-other

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Organometallic-Organic Hybrid Polymers Assembled from Pentaphosphaferrocene, Bipyridyl Linkers, and CuI Ions.

Moussa Mehdi Elsayed ME Welsch Stefan S Lochner Matthias M Peresypkina Eugenia V EV Virovets Alexander V AV Scheer Manfred M

European journal of inorganic chemistry 20180611 23

A multicomponent approach of the P n ligand complex [Cp*Fe(η5-P5)] (1: Cp* = η5-C5Me5) with the ditopic organic linkers 4,4'-bipyridine (2) or trans-1,2-di(pyridine-4-yl)ethene (3) in the presence of CuI salts of the anions [BF4]- and [PF6]- or the coordinating anion Br-, leads to the formation of four novel organometallic-organic ...[more]

PMID: 30034271

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