Ontology highlight
ABSTRACT:
SUBMITTER: Yuan N
PROVIDER: S-EPMC6277383 | biostudies-other | 2018 Dec
REPOSITORIES: biostudies-other
Yuan Ning N Church Tamara L TL Brandt Erik G EG Hedin Niklas N Zou Xiaodong X Bernin Diana D
Scientific reports 20181203 1
Postsynthetic reactions of metal-organic frameworks (MOFs) are versatile tools for producing functional materials, but the methods of evaluating these reactions are cumbersome and destructive. Here we demonstrate and validate the use of in situ NMR spectroscopy of species in the liquid state to examine solvent-assisted ligand exchange (SALE) and postsynthetic modification (PSM) reactions of metal-organic frameworks. This technique allows functionalization to be monitored over time without decomp ...[more]