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Electrophoresis Assembly of Novel Superhydrophobic Molybdenum Trioxide (MoO₃) Films with Great Stability.

ABSTRACT: This work presents a hydrothermal synthesis approach to produce novel schistose molybdenum trioxide (MoO₃) powders with wide application, and introduces a facile electrophoresis assembly technique to construct the superhydrophobic MoO₃ films (SMFs) with contact angle up to 169 ± 1° at normal pressure and temperature. The microstructures and chemical compositions of product were analyzed by field emission scanning electron microcopy (FESEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD). The wettability and stability studies indicate that the SMFs all show great resistance in various environments with adjusting factors, including droplets with different surface tension, pH, relative humidity, etc., and the stability can be maintained at least for five months. Notably, this paper will provides a valuable reference for designing novel oxide powders and their high-efficient hydrophobic film formation with self-cleaning or water proof properties.

SUBMITTER: Guo X

PROVIDER: S-EPMC6384839 | biostudies-other | 2019 Jan

REPOSITORIES: biostudies-other

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Electrophoresis Assembly of Novel Superhydrophobic Molybdenum Trioxide (MoO₃) Films with Great Stability.

Guo Xiaogang X Liang Taotao T

Materials (Basel, Switzerland) 20190122 3

This work presents a hydrothermal synthesis approach to produce novel schistose molybdenum trioxide (MoO₃) powders with wide application, and introduces a facile electrophoresis assembly technique to construct the superhydrophobic MoO₃ films (SMFs) with contact angle up to 169 ± 1° at normal pressure and temperature. The microstructures and chemical compositions of product were analyzed by field emission scanning electron microcopy (FESEM), energy dispersive X-ray spectroscopy (EDX), X-ray diffr ...[more]

PMID: 30678163

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Project description:We report an approach to the fabrication of superhydrophobic thin films that is based on the 'reactive' layer-by-layer assembly of azlactone-containing polymer multilayers. We demonstrate that films fabricated from alternating layers of the azlactone functionalized polymer poly(2-vinyl-4,4-dimethylazlactone) (PVDMA) and poly(ethyleneimine) (PEI) exhibit micro- and nanoscale surface features that result in water contact angles in excess of 150º. Our results reveal that the formation of these surface features is (i) dependent upon film thickness (i.e., the number of layers of PEI and PVDMA deposited) and (ii) that it is influenced strongly by the presence (or absence) of cyclic azlactone-functionalized oligomers that can form upon storage of the 2-vinyl-4,4-dimethylazlactone (VDMA) used to synthesize PVDMA. For example, films fabricated using polymers synthesized in the presence of these oligomers exhibited rough, textured surfaces and superhydrophobic behavior (i.e., advancing contact angles in excess of 150º). In contrast, films fabricated from PVDMA polymerized in the absence of this oligomer (e.g., using freshly distilled monomer) were smooth and only moderately hydrophobic (i.e., advancing contact angles of ~75º). The addition of authentic, independently synthesized oligomer to samples of distilled VDMA at specified and controlled concentrations permitted reproducible fabrication of superhydrophobic thin films on the surfaces of a variety of different substrates. The surfaces of these films were demonstrated to be superhydrophobic immediately after fabrication, but they became hydrophilic after exposure to water for six days. Additional experiments demonstrated that it was possible to stabilize and prolong the superhydrophobic properties of these films (e.g., advancing contact angles in excess of 150° even after complete submersion in water for at least six weeks) by exploiting the reactivity of residual azlactones to functionalize the surfaces of the films using hydrophobic amines (e.g., aliphatic or semi-fluorinated aliphatic amines). Our results demonstrate a straightforward and substrate-independent approach to the design of superhydrophobic and reactive polymer-based coatings of potential use in a broad range of fundamental and applied contexts.

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Electrophoresis Assembly of Novel Superhydrophobic Molybdenum Trioxide (MoO₃) Films with Great Stability.

Publications

Electrophoresis Assembly of Novel Superhydrophobic Molybdenum Trioxide (MoO₃) Films with Great Stability.

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