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Tailoring Energy Transfer in Mixed Eu/Tb Metal-Organic Frameworks for Ratiometric Temperature Sensing.


ABSTRACT: Eu/Tb metal-organic frameworks (Eu/Tb-MOFs), exhibiting Eu3+ and Tb3+ emissions, stand out as some of the most fascinating luminescent thermometers. As the relative thermal sensitivity model is limited to its lack of precision for fitting ratio of Eu3+ and Tb3+ emissions, accurately predicting the sensing performance of Eu/Tb-MOFs remains a significant challenge. Herein, we report a series of luminescent Eu/Tb-MOF thermometers, EuxTb1-xL, with excellent thermal sensitivity around physiological levels, achieved through the tuning energy transfer from ligands to Eu3+ and Tb3+ and between the Ln ions. It was found that the singlet lowest-energy excited state (S1) of the ligand and the higher triplet energy level (Tn) are crucial in the energy transfer processes of ligand→Tb3+ and ligand→Eu3+. This enables EuxTb1-xL to serve as an effective platform for exploring the impact of these energy transfer processes on the temperature-sensing properties of luminescent Eu/Tb-MOF thermometers. The relative thermal sensitivity is comparable to that of dual-center MOF-based luminescent thermometers operating at physiological levels. This study provides valuable insights into the design of new Eu/Tb thermometers and the accurate prediction of their sensing performance.

SUBMITTER: Tang H 

PROVIDER: S-EPMC11357012 | biostudies-literature | 2024 Aug

REPOSITORIES: biostudies-literature

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Tailoring Energy Transfer in Mixed Eu/Tb Metal-Organic Frameworks for Ratiometric Temperature Sensing.

Tang Hui H   Cheng Siyuan S   Zhang Zhihui Z   He Mingyang M   Qian Junfeng J   Li Liang L  

Molecules (Basel, Switzerland) 20240819 16


Eu/Tb metal-organic frameworks (Eu/Tb-MOFs), exhibiting Eu<sup>3+</sup> and Tb<sup>3+</sup> emissions, stand out as some of the most fascinating luminescent thermometers. As the relative thermal sensitivity model is limited to its lack of precision for fitting ratio of Eu<sup>3+</sup> and Tb<sup>3+</sup> emissions, accurately predicting the sensing performance of Eu/Tb-MOFs remains a significant challenge. Herein, we report a series of luminescent Eu/Tb-MOF thermometers, Eu<sub>x</sub>Tb<sub>1-x  ...[more]

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