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Cis-dihydroxylation of unsaturated potassium alkyl- and aryltrifluoroborates.


ABSTRACT: [reaction: see text] The cis-dihydroxylation of olefin-containing potassium alkyl- and aryltrifluoroborates proceeds readily in moderate to excellent yields. The resulting diols are efficient coupling partners in Suzuki-Miyaura-type reactions with both alkenyl and aryl bromides.

SUBMITTER: Molander GA 

PROVIDER: S-EPMC2504008 | biostudies-literature | 2006 Jan

REPOSITORIES: biostudies-literature

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cis-dihydroxylation of unsaturated potassium alkyl- and aryltrifluoroborates.

Molander Gary A GA   Figueroa Ruth R  

Organic letters 20060101 1


[reaction: see text] The cis-dihydroxylation of olefin-containing potassium alkyl- and aryltrifluoroborates proceeds readily in moderate to excellent yields. The resulting diols are efficient coupling partners in Suzuki-Miyaura-type reactions with both alkenyl and aryl bromides. ...[more]

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