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A convergent and enantioselective synthesis of (+)-amurensinine via selective C-H and C-C bond insertion reactions.

ABSTRACT: A convergent and enantioselective synthesis of the natural product amurensinine is described. The synthetic strategy takes advantage of mild and selective C-H and C-C bond insertion reactions, in addition to the palladium-catalyzed aerobic oxidative kinetic resolution recently developed in these laboratories.

SUBMITTER: Tambar UK

PROVIDER: S-EPMC2529249 | biostudies-literature | 2006 Sep

REPOSITORIES: biostudies-literature

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A convergent and enantioselective synthesis of (+)-amurensinine via selective C-H and C-C bond insertion reactions.

Tambar Uttam K UK Ebner David C DC Stoltz Brian M BM

Journal of the American Chemical Society 20060901 36

A convergent and enantioselective synthesis of the natural product amurensinine is described. The synthetic strategy takes advantage of mild and selective C-H and C-C bond insertion reactions, in addition to the palladium-catalyzed aerobic oxidative kinetic resolution recently developed in these laboratories. ...[more]

PMID: 16953603

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