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Synthesis of novel photochromic pyrans via palladium-mediated reactions.


ABSTRACT: Photochromic pyrans for applications in material and life sciences were synthesized via palladium-mediated cyanation, carbonylation and Sonogashira cross-coupling starting from bromo-substituted naphthopyran 1 and benzopyrans 2a/b. A novel photoswitchable benzopyran-based omega-amino acid 6 for Fmoc-based solid-phase peptide synthesis is presented. The photochromic behaviour of the 3-cyano-substituted benzopyran 5a was investigated by time-resolved absorption spectroscopy in the picosecond time domain.

SUBMITTER: Bottcher C 

PROVIDER: S-EPMC2707076 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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Synthesis of novel photochromic pyrans via palladium-mediated reactions.

Böttcher Christoph C   Zeyat Gehad G   Ahmed Saleh A SA   Irran Elisabeth E   Cordes Thorben T   Elsner Cord C   Zinth Wolfgang W   Rueck-Braun Karola K  

Beilstein journal of organic chemistry 20090527


Photochromic pyrans for applications in material and life sciences were synthesized via palladium-mediated cyanation, carbonylation and Sonogashira cross-coupling starting from bromo-substituted naphthopyran 1 and benzopyrans 2a/b. A novel photoswitchable benzopyran-based omega-amino acid 6 for Fmoc-based solid-phase peptide synthesis is presented. The photochromic behaviour of the 3-cyano-substituted benzopyran 5a was investigated by time-resolved absorption spectroscopy in the picosecond time  ...[more]

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