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ABSTRACT:
SUBMITTER: Diez PS
PROVIDER: S-EPMC2912438 | biostudies-literature | 2010 Jul
REPOSITORIES: biostudies-literature
Diez Peter S PS Micalizio Glenn C GC
Journal of the American Chemical Society 20100701 28
A convergent synthesis of highly substituted and stereodefined skipped polyenes is described from the reductive cross-coupling of substituted 1,5-diene-3-ols with alkynes. The control of site selectivity in functionalization of the substituted diene is a central feature of this complex fragment union reaction. ...[more]