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Decachloro-hexa-1,5-diene.

ABSTRACT: The title compound, C(6)Cl(10), cystallizes in a nearly C2-symmetrical gauche conformation. Both trichloro-vinyl groups are nearly planar [Cl-C-C-Cl torsion angles = -178.47?(12) and -179.93?(11)°] and the lengths of their C-Cl bonds increase from the terminal trans and cis C-Cl bonds to the inter-nal bonds. The Cl-C-Cl bond angles of the terminal dichloro-methyl-ene units are compressed to 111.75?(11) and 111.40?(11)°.

SUBMITTER: Schollmeyer D 

PROVIDER: S-EPMC3379281 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Decachloro-hexa-1,5-diene.

Schollmeyer Dieter D   Detert Heiner H  

Acta crystallographica. Section E, Structure reports online 20120512 Pt 6

The title compound, C(6)Cl(10), cystallizes in a nearly C2-symmetrical gauche conformation. Both trichloro-vinyl groups are nearly planar [Cl-C-C-Cl torsion angles = -178.47 (12) and -179.93 (11)°] and the lengths of their C-Cl bonds increase from the terminal trans and cis C-Cl bonds to the inter-nal bonds. The Cl-C-Cl bond angles of the terminal dichloro-methyl-ene units are compressed to 111.75 (11) and 111.40 (11)°. ...[more]

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