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Cis-Bis[2-(cyclo-propyl-imino-meth-yl)-6-methoxy-phenolato]bis-(thio-cyanato)cobalt(II).

ABSTRACT: In the title compound, [Co(NCS)(2)(C(11)H(13)NO(2))(2)], a mononuclear Schiff base cobalt(II) complex, the Co atom is six-coordinated by four O atoms from two Schiff base ligands, and by two N atoms from two thio-cyanate ligands, forming a distorted octa-hedral geometry. The central Co atom lies on a twofold rotation axis. An intramolecular N-H⋯O hydrogen bond is present.

SUBMITTER: Wang SX

PROVIDER: S-EPMC2914956 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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cis-Bis[2-(cyclo-propyl-imino-meth-yl)-6-methoxy-phenolato]bis-(thio-cyanato)cobalt(II).

Wang Shou-Xing SX

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

In the title compound, [Co(NCS)(2)(C(11)H(13)NO(2))(2)], a mononuclear Schiff base cobalt(II) complex, the Co atom is six-coordinated by four O atoms from two Schiff base ligands, and by two N atoms from two thio-cyanate ligands, forming a distorted octa-hedral geometry. The central Co atom lies on a twofold rotation axis. An intramolecular N-H⋯O hydrogen bond is present. ...[more]

PMID: 21200646

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