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Cis-Bis[2-(cyclo-propyl-imino-meth-yl)-6-methoxy-phenolato]bis-(thio-cyanato)cobalt(II).

ABSTRACT: In the title compound, [Co(NCS)(2)(C(11)H(13)NO(2))(2)], a mononuclear Schiff base cobalt(II) complex, the Co atom is six-coordinated by four O atoms from two Schiff base ligands, and by two N atoms from two thio-cyanate ligands, forming a distorted octa-hedral geometry. The central Co atom lies on a twofold rotation axis. An intramolecular N-H⋯O hydrogen bond is present.

SUBMITTER: Wang SX

PROVIDER: S-EPMC2914956 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Bis[2-(cyclo-propyl-imino-meth-yl)-5-methoxy-phenolato]zinc(II).

Project description:In the title complex, [Zn(C(11)H(12)NO(2))(2)], the Zn(2+) ion (site symmetry 2) is coordinated by two N,O-bidentate Schiff base ligands, generating a tetra-hedral ZnO(2)N(2) geometry for the metal ion.

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Project description:The asymmetric unit of the title complex, [Ni(NCS)(2)(C(13)H(20)N(2)O(2))(2)], consists of two half-mol-ecules, both of which are completed by crystallographic inversion symmetry (Ni(2+) site symmetry = in both cases). Both metal ions are six-coordinated in distorted trans-NiO(2)N(4) geometries arising from two N,O-bidentate Schiff base ligands and two N-bonded thio-cyanate ions. The mol-ecular conformations are reinforced by two intra-molecular N-H?O hydrogen bonds.

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Bis[2-(cyclo-hexyl-imino-meth-yl)-5-methoxy-phenolato]copper(II).

Project description:In the title centrosymmetric mononuclear complex, [Cu(C(14)H(18)NO(2))(2)], the Cu(II) ion, lying on an inversion centre, is four-coordinated by two imine N and two phenolate O atoms from two Schiff base ligands, forming a slightly distorted square-planar geometry.

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Project description:In the title mononuclear nickel(II) complex, [Ni(C(12)H(17)N(2)O(2))(NCS)], the metal atom is four-coordinated in a tetra-hedrally distorted square-planar geometry by the phenolate O atom, the imine N atom and the amine N atom of the Schiff base ligand and by the N atom of a thio-cyanate ligand. In the crystal structure, centrosymmetrically related mol-ecules are linked into dimers through inter-molecular N-H⋯O hydrogen bonds. These dimers are further connected by inter-molecular C-H⋯S hydrogen bonds, forming chains running parallel to [101].

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Bis(2-hydroxy-imino-methyl-6-methoxy-phenolato-κO,N)cobalt(II).

Project description:In the title compound, [Co(C(8)H(8)NO(3))(2)], the Co(II) atom lies on a centre of inversion and is coordinated in a slightly distorted square-planar geometry by two N and two O atoms from the 2-hydroxy-imino-methyl-6-methoxy-phenolate ligands. Intra-molecular O-H⋯O hydrogen bonds are formed and the complexes form stacks along the b axis, with an inter-planar separation of 3.332 (1) Å between complexes. Pairs of C-H⋯O contacts are formed between complexes in neighbouring stacks.

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Bis[2,4-dibromo-6-(n-propyl-imino-methyl)phenolato-κN,O]cobalt(II).

Project description:In the title complex, [Co(C(10)H(10)Br(2)NO)(2)], the Co(II) atom lies on a twofold rotation axis, the N(2)O(2) units having distorted tetra-hedral coordination environments comprising two bidentate chelate 2,4-dibromo-6-(n-propyl-imino-meth-yl)phenolate Schiff base ligands [Co-N = 1.989 (3) Å, Co-O = 1.924 (2) Å and O/N-Co-O/N = 94.53 (10)-125.40 (15)°]. In the crystal structure, the mol-ecules are linked via weak inter-molecular C-H⋯O hydrogen bonds [3.334 (5) Å] and there are also short inversion-related intermolecular Br⋯Br contacts [3.4263 (6) Å].

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Project description:In the title mononuclear copper(II) complex, [Cu(C(12)H(17)N(2)O(2))(NCS)], the Cu(II) atom is four-coordinated by an NNO-donor set of the tridentate Schiff base ligand and the N atom of a terminal thio-cyanate ligand in a slightly distorted square-planar geometry.

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Project description:The Schiff base 2-[(4-methyl-phen-yl)imino-meth-yl]-6-methoxy-phenol (HL) forms a complex with a Zn(2+) atom and two independent thio-cyanate ions, [Zn(NCS)(2)(C(15)H(15)NO(2))(2)], in which two phenolate O atoms the two independent Schiff base ligands are coordinated to thee Zn(2+) atom. The protonated imine N atoms are involved in an intramolecular hydrogen bond with the phenoxide group. The Zn atom is also coordinated by two N atoms of two thio-cyanate ligands. The coordination environment of the Zn atom is distorted-tetra-hedral.

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Bis(2-cyclo-hexyl-imino-methyl-4,6-dihydro-seleno-phenolato)cobalt(II) acetonitrile solvate.

Project description:In the title compound, [Co(C(13)H(16)NOSe(2))(2)]·CH(3)CN, the Co(II) atom is four-coordinated by two N,O-bidentate Schiff base ligands, resulting in a distorted tetra-hedral coordination for the metal ion.

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