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Bis[2,4-dibromo-6-(n-propyl-imino-methyl)phenolato-?N,O]cobalt(II).

ABSTRACT: In the title complex, [Co(C(10)H(10)Br(2)NO)(2)], the Co(II) atom lies on a twofold rotation axis, the N(2)O(2) units having distorted tetra-hedral coordination environments comprising two bidentate chelate 2,4-dibromo-6-(n-propyl-imino-meth-yl)phenolate Schiff base ligands [Co-N = 1.989?(3)?Å, Co-O = 1.924?(2)?Å and O/N-Co-O/N = 94.53?(10)-125.40?(15)°]. In the crystal structure, the mol-ecules are linked via weak inter-molecular C-H?O hydrogen bonds [3.334?(5)?Å] and there are also short inversion-related intermolecular Br?Br contacts [3.4263?(6)?Å].

SUBMITTER: Li C 

PROVIDER: S-EPMC3008039 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

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Bis[2,4-dibromo-6-(n-propyl-imino-methyl)phenolato-κN,O]cobalt(II).

Li Chunyan C   Li Rui R   Zhang Shufang S  

Acta crystallographica. Section E, Structure reports online 20100818 Pt 9

In the title complex, [Co(C(10)H(10)Br(2)NO)(2)], the Co(II) atom lies on a twofold rotation axis, the N(2)O(2) units having distorted tetra-hedral coordination environments comprising two bidentate chelate 2,4-dibromo-6-(n-propyl-imino-meth-yl)phenolate Schiff base ligands [Co-N = 1.989 (3) Å, Co-O = 1.924 (2) Å and O/N-Co-O/N = 94.53 (10)-125.40 (15)°]. In the crystal structure, the mol-ecules are linked via weak inter-molecular C-H⋯O hydrogen bonds [3.334 (5) Å] and there are also short inver  ...[more]

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