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Bis(2-hydroxy-imino-methyl-6-methoxy-phenolato-?O,N)cobalt(II).

ABSTRACT: In the title compound, [Co(C(8)H(8)NO(3))(2)], the Co(II) atom lies on a centre of inversion and is coordinated in a slightly distorted square-planar geometry by two N and two O atoms from the 2-hydroxy-imino-methyl-6-methoxy-phenolate ligands. Intra-molecular O-H?O hydrogen bonds are formed and the complexes form stacks along the b axis, with an inter-planar separation of 3.332?(1)?Å between complexes. Pairs of C-H?O contacts are formed between complexes in neighbouring stacks.

SUBMITTER: Zhang SH 

PROVIDER: S-EPMC2960033 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Bis(2-hydroxy-imino-methyl-6-methoxy-phenolato-κO,N)cobalt(II).

Zhang Shu Hua SH   Ge Cheng Min CM   Feng Chao C  

Acta crystallographica. Section E, Structure reports online 20081129 Pt 12

In the title compound, [Co(C(8)H(8)NO(3))(2)], the Co(II) atom lies on a centre of inversion and is coordinated in a slightly distorted square-planar geometry by two N and two O atoms from the 2-hydroxy-imino-methyl-6-methoxy-phenolate ligands. Intra-molecular O-H⋯O hydrogen bonds are formed and the complexes form stacks along the b axis, with an inter-planar separation of 3.332 (1) Å between complexes. Pairs of C-H⋯O contacts are formed between complexes in neighbouring stacks. ...[more]

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