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[N-(5-Chloro-2-oxidobenzylidene)valinato-κO,N,O']dicyclo-hexyl-tin(IV).

ABSTRACT: The tin atom of the title compound, [Sn(C(6)H(11))(2)(C(12)H(12)ClNO(3))], adopts a distorted SnNC(2)O(2) trigonal-bipyramidal geometry, and forms five- and six-membered chelate rings with the tridentate ligand.

SUBMITTER: Li JP

PROVIDER: S-EPMC2914970 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Dicyclo-hexyl[N-(3-meth-oxy-2-oxido-benzyl-idene)valinato-?O,N,O']tin(IV).

Project description:In the title compound, [Sn(C(6)H(11))(2)(C(13)H(15)NO(4))], the Sn atom is five-coordinate and adopts a distorted trigonal-bipyramidal SnNC(2)O(2) geometry with the O atoms in axial positions. The metal atom forms five- and six-membered chelate rings with the O,N,O'-tridentate ligand. The two cyclo-hexyl groups bound to the Sn atom adopt chair conformations, with the Sn-C bonds in equatorial positions and a mean Sn-C distance of 2.138?(3)?Å.

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Dicyclo-hexyl-ammonium bis-(chloro-difluoro-acetato-?O)cyclo-hexyl-diphenyl-stannate(IV).

Project description:In the title mixed-organyl stannate, (C(12)H(24)N)[Sn(C(6)H(5))(2)(C(6)H(11))(CClF(2)O(2))(2)], there are two cations and two anions in the asymmetric unit. Each five-coordinate Sn atom shows trans-C(3)SnO(2) trigonal bipyramidal coordination. The four Sn-O distances are approximately equal in the two independent anions. Each ammonium cation serves as a hydrogen-bond donor to two stannates, the hydrogen-bonding inter-actions giving rise to linear hydrogen-bonded chains.

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Dicyclo-hexyl-ammonium bis-(chloro-difluoro-acetato-?O)cyclo-pentyl-diphenyl-stannate(IV).

Project description:The five-coordinate Sn atom in the title mixed organyl stannate compound, (C(12)H(24)N)[Sn(C(5)H(9))(C(6)H(5))(2)(C(2)ClF(2)O(2))], is in a trans-C(3)SnO(2) trigonal-bipyramidal coordination environment. The NH(2) groups of the cations act as hydrogen-bond donors to two symmetry-related anions, resulting in the formation of linear chains. One of the phenyl rings is disordered over two sites with equal occupancies.

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Bis(μ-chloroacetato-κO:O')bis(chloro-acetato-κO)di-μ(3)-oxido-tetrakis[dibenzyl-tin(IV)].

Project description:The title tetra-nuclear complex mol-ecule, [Sn(4)(C(7)H(7))(8)(C(2)H(2)ClO(2))(4)O(2)], has crystallographically imposed inversion symmetry. Each Sn atom has a distorted trigonal-bipyramidal geometry, with the equatorial plane formed by an oxido O atom and two C atoms of two benzyl anions. The configuration of the complex is stabilized by a pair of C-H⋯O hydrogen bonds. In the crystal, complex mol-ecules are linked into zigzag chains along [110] by C-H⋯O hydrogen bonds.

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Dicyclo-hexyl-{3-hydr-oxy-N'-[1-(2-oxidophenyl-?O)ethyl-idene]-2-naphthohydrazidato-?N',O}tin(IV).

Project description:In the title compound, [Sn(C(6)H(11))(2)(C(19)H(14)N(2)O(3))], the Sn(IV) atom is O,N,O' chelated by the deprotonated Schiff base ligand and exists in a cis-trigonal-bipyramidal environment, completed by the two cyclohexyl ligands.

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(?(6)-Benzene)-dichlorido-(chloro-dicyclo-hexyl-phosphane-?P)ruthenium(II) chloro-form monosolvate.

Project description:The title compound, [RuCl2(?(6)-C6H6)(C12H22ClP)]·CHCl3, was prepared by reaction of [RuCl2(?(6)-C6H6)]2 with chloro-dicyclo-hexyl-phosphane in CHCl3 at 323?K under argon. The Ru(II) atom is surrounded by one arene ligand, two Cl atoms and a phosphane ligand in a piano-stool geometry. The phosphane ligand is linked by the P atom, with an Ru-P bond length of 2.3247?(4)?Å. Both cyclo-hexyl rings at the P atom adopt a chair conformation. In the crystal, the Ru(II) complex mol-ecule and the chloro-form solvent mol-ecule are linked by a bifurcated C-H?(Cl,Cl) hydrogen bond. Intra-molecular C-H?Cl hydrogen bonds are also observed.

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Chlorido(dimethyl sulfoxide-κO)triphenyl-tin(IV).

Project description:In the title compound, [Sn(C(6)H(5))(3)Cl(C(2)H(6)OS)], the Sn(IV) atom is coordinated by three phenyl groups, a chloride ion and a dimethyl sulfoxide mol-ecule in a distorted trigonal-bipyramidal geometry. In the crystal, adjacent mol-ecules are linked through inter-molecular C-H⋯Cl hydrogen bonds, weak C-H⋯π inter-actions and π-π inter-actions [centroid-centroid distance = 3.934 (3) Å. An intra-molecular C-H⋯π inter-action is also observed.

| S-EPMC2971969 | biostudies-literature

(Ferrocene-carboxyl-ato-κO)triphenyl-tin(IV).

Project description:In the title compound, [FeSn(C(5)H(5))(C(6)H(5))(3)(C(6)H(4)O(2))], the Sn(IV) atom displays a distorted tetra-hedral coordination geometry, provided by one O atom of the monodentate ferrocene-carboxyl-ate ligand [Sn-O = 2.079 (2) Å] and by three C atoms of the three phenyl groups [average Sn-C = 2.130 (4) Å]. No classic hydrogen bonds or inter-molecular inter-actions are observed in the crystal.

| S-EPMC3006984 | biostudies-literature

(Methanol-κO)(2-methyl-3-nitro-benzoato-κO)triphenyl-tin(IV).

Project description:The five-coordinate Sn atom in the title compound, [Sn(C(6)H(5))(3)(C(8)H(6)NO(4))(CH(3)OH)], exists in a trans-C(3)SnO(2) trigonal-bipyramidal coordination polyhedron of which the O atoms of the methanol mol-ecule and carboxyl-ate group occupy the apical sites. In the crystal, adjacent mol-ecules are linked by inter-molecular O-H⋯O inter-actions, generating a helical hydrogen-bonded chain running along the b axis.

| S-EPMC3007999 | biostudies-literature

Dicyclo-hexyl-ammonium trimethyl-bis-(hydrogen phenyl-phospho-nato)stannate(IV).

Project description:In the title compound, (C(12)H(24)N)[Sn(CH(3))(3)(C(6)H(6)O(3)P)(2)], the SnMe(3) residues are axially coordinated by two monodentate [PhPO(3)H](-) anions, leading to a trigonal-bipyramidal geometry for the Sn(IV) atom. The two [SnMe(3)(PhPO(3)H)(2)](-) anions in the unit cell are associated into infinite chains along the a axis by O-H?O hydrogen bonds involving the hy-droxy group of the hydrogen phenyl-phospho-nate ion. The chains inter-act with one another via O-H?O hydrogen bonds along the c axis. These networks of anions assemble with the dicyclo-hexyl-ammonium ion through N-H?O hydrogen bonds, forming a three-dimensional network.

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