Browse
Submit Data
Databases
API
Help

Dataset Information

16 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis(chloro-acetato-?O,O')bis-(2-fluoro-benzyl-?C)tin(IV).

ABSTRACT: In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(7)H(6)F)(2)], the Sn(IV) atom is located on a twofold rotation axis and forms a strongly distorted trans-octa-hedral geometry. The equatorial plane is defined by two chelating chloro-acetate ligands with asymmetrical Sn-O bond lengths, while the axial positions are occupied by the C atoms of two 2-fluoro-benzyl groups. In the crystal, infinite chains in the [010] direction are formed through inter-molecular Sn?O inter-actions [Sn?O separation = 3.682?(3)?Å].

SUBMITTER: Deng A

PROVIDER: S-EPMC3238784 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis(chloro-acetato-κO,O')bis-(2-fluoro-benzyl-κC)tin(IV).

Deng Aixia A Teng Mouyong M Xie Qian Q Yan Nana N

Acta crystallographica. Section E, Structure reports online 20111130 Pt 12

In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(7)H(6)F)(2)], the Sn(IV) atom is located on a twofold rotation axis and forms a strongly distorted trans-octa-hedral geometry. The equatorial plane is defined by two chelating chloro-acetate ligands with asymmetrical Sn-O bond lengths, while the axial positions are occupied by the C atoms of two 2-fluoro-benzyl groups. In the crystal, infinite chains in the [010] direction are formed through inter-molecular Sn⋯O inter-actions [Sn⋯O separation = 3.68 ...[more]

PMID: 22199661

Similar Datasets

Bis-(chloro-acetato-?O)bis(trimethyl-silylmethyl)tin(IV).

Project description:In the title complex, [Sn(C(2)H(2)ClO(2))(2)(C(4)H(11)Si)(2)], the Sn(IV) ion is coordinated in a distorted tetra-hedral environment formed by two O atoms from two monodenate chloro-acetato ligands and two C atoms from two trimethyl silyl ligands. Two further weak intra-molecular Sn?O contacts [2.744?(2) and 2.655?(2)?Å] are formed by the chloro-acetato ligands.

| S-EPMC3200893 | biostudies-other

Bis[2-(3-chloro-benzyl-idene)propanoato-?O,O']diethyl-tin(IV).

Project description:In the mol-ecule of the title compound, [Sn(C(2)H(5))(2)(C(10)H(8)ClO(2))(2)], the Sn atom is six-coordinated in a distorted tetra-gonal-bipyramidal configuration by four O atoms in the equatorial plane and two C atoms in the axial positions. Intra-molecular C-H?O hydrogen bonds result in the formation of two planar and two non-planar five-membered rings; the latter adopt envelope conformations. There are weak ?-? inter-actions between aromatic rings, with centroid-to-centroid distances of 3.796?(2) and 4.171?(2)?Å. There is also a single C-Cl?? inter-action [C-Cl = 1.740?(4), Cl?? = 3.795?(2) C?? = 3.697?(4)?Åand C-Cl?\p =73.45?(11)°].

| S-EPMC2961729 | biostudies-literature

catena-Poly[[chloridodimethyl-tin(IV)]-?-chloro-acetato-?O:O'].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(2)(C(2)H(2)ClO(2))Cl](n), the Sn atom has a distorted trigonal-bipyramidal geometry, with two O atoms of the ligands in axial positions and two methyl groups and one Cl atom in equatorial positions. Adjacent Sn atoms are bridged by the two O atoms of the carboxylate ligand, forming a chain structure along the a-axis direction.

| S-EPMC3238711 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-2-(2-chloro-phenyl)-acetato].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(8)H(6)ClO(2))](n), the Sn atoms exhibit a distorted trigonal-bipyramidal geometry with the carboxyl-ate O atoms of the 2-chloro-phenyl-acetato ligands in axial positions and with the equatorial sites occupied by the three methyl groups. Adjacent Sn atoms are bridged by coordination to the two O atoms of each 2-chloro-phenyl-acetato ligand, forming a chain structure.

| S-EPMC2970316 | biostudies-literature

Bis(dimethyl sulfoxide-?O)bis-(mercapto-acetato-?O,S)tin(IV).

Project description:In the title compound, [Sn(C(2)H(2)O(2)S)(2)(C(2)H(6)OS)(2)], the mercaptoacetato ligands chelate to Sn(IV) through S and one O atoms. The metal centre is also coordinated by two dimethyl sulfoxide (DMSO) ligands through the O atom, leading to an overall distorted octahedral coordination environment for the Sn(IV) atom. The mol-ecular adduct lies on a twofold rotation axis.

| S-EPMC2971123 | biostudies-literature

Bis(benzyl phenyl sulfoxide-?O)dichloridodiphenyl-tin(IV).

Project description:The mol-ecule of the title compound, [Sn(C(6)H(5))(2)Cl(2)(C(13)H(12)OS)(2)], has crystallographic twofold symmetry. The Sn(IV) atom is six-coordinate within a distored octa-hedral geometry defined by a C(2)Cl(2)O(2) donor set.

| S-EPMC2971230 | biostudies-literature

Bis(?-chloroacetato-?O:O')bis(chloro-acetato-?O)di-?(3)-oxido-tetrakis[dibenzyl-tin(IV)].

Project description:The title tetra-nuclear complex mol-ecule, [Sn(4)(C(7)H(7))(8)(C(2)H(2)ClO(2))(4)O(2)], has crystallographically imposed inversion symmetry. Each Sn atom has a distorted trigonal-bipyramidal geometry, with the equatorial plane formed by an oxido O atom and two C atoms of two benzyl anions. The configuration of the complex is stabilized by a pair of C-H?O hydrogen bonds. In the crystal, complex mol-ecules are linked into zigzag chains along [110] by C-H?O hydrogen bonds.

| S-EPMC3051761 | biostudies-other

trans-Di-chlorido-bis-(dimethyl sulfoxide-?O)bis-(4-fluoro-benzyl-?C1)tin(IV): crystal structure and Hirshfeld surface analysis.

Project description:The SnIV atom in the title diorganotin compound, [Sn(C7H6F)2Cl2(C2H6OS)2], is located on a centre of inversion, resulting in the C2Cl2O2 donor set having an all-trans disposition of like atoms. The coordination geometry approximates an octa-hedron. The crystal features C-H?F, C-H?Cl and C-H?? inter-actions, giving rise to a three-dimensional network. The respective influences of the Cl?H/H?Cl and F?H/H?F contacts to the mol-ecular packing are clearly evident from the analysis of the Hirshfeld surface.

| S-EPMC5418780 | biostudies-literature

Octa-kis(2-chloro-benz-yl)di-?(2)-hydroxido-di-?(3)-oxido-bis-(2-phenyl-acetato)tetra-tin(IV).

Project description:The asymmetric unit of the title compound, [Sn(4)(C(7)H(6)Cl)(8)(C(8)H(7)O(2))(2)O(2)(OH)(2)], comprises one-half of the centrosymmetric tin(IV) complex. ?(3)-Oxide and ?(2)-hydroxide bridges link the four five-coordinate Sn(IV) atoms to generate three fused four-membered Sn-O-Sn-O rings in a ladder-like structure. The two endocyclic Sn atoms each bind to two ?(3)-oxide anions and a ?(2)-hydroxide ligand, together with two 2-chloro-benzyl groups. The exocyclic Sn atoms each carry a monodentate phenyl-acetate ligand, two 2-chloro-benzyl groups, and ?(3)-oxide and ?(2)-hydroxide ligands. Both types of Sn atoms adopt a distorted trigonal-bipyramidal coordination geometry. The mol-ecular conformation is stabilized by intra-molecular O-H?O inter-actions involving the ?(2)-hydroxide ligands and the C=O group of the phenyl-acetate ligand.

| S-EPMC2979133 | biostudies-literature

Chloridotris(4-chloro-benzyl-?C)(triphenyl-arsine oxide-?O)tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(7)H(6)Cl)(3)Cl(C(18)H(15)AsO)], shows a distorted C(3)ClOSn trigonal bipyramidal coordination; the axial O-Sn-Cl angle is 170.22?(4)°.

| S-EPMC2969448 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data