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Bis(2-amino-4-chloro-benzoato)triphenyl-anti-mony(V).

ABSTRACT: The title complex mol-ecule, [Sb(C(6)H(5))(3)(C(7)H(5)ClNO(2))(2)], possesses crystallographically imposed C(2) symmetry. The Sb atom exhibits a trigonal-bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl-ate groups and the equatorial positions by the C atoms of the phenyl groups. Intra-molecular N-H?O and C-H?O hydrogen bonds occur.

SUBMITTER: Wen L

PROVIDER: S-EPMC2971026 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Bis(2-amino-4-chloro-benzoato)triphenyl-anti-mony(V).

Wen Liyuan L Yin Handong H Wang Chuanhua C

Acta crystallographica. Section E, Structure reports online 20091028 Pt 11

The title complex mol-ecule, [Sb(C(6)H(5))(3)(C(7)H(5)ClNO(2))(2)], possesses crystallographically imposed C(2) symmetry. The Sb atom exhibits a trigonal-bipyramidal geometry with the axial positions occupied by the O atoms of two carboxyl-ate groups and the equatorial positions by the C atoms of the phenyl groups. Intra-molecular N-H⋯O and C-H⋯O hydrogen bonds occur. ...[more]

PMID: 21578173

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