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Catena-Poly[[silver(I)-?-N-(3-pyridyl-meth-yl)pyridine-4-carboxamide] nitrate monohydrate].

ABSTRACT: In the title compound, {[Ag(C(12)H(11)N(3)O)]NO(3)·H(2)O}(n), the Ag atom is coordinated by two N atoms from the heterocyclic ligand, giving a linear polycationic chain. Two long Ag?O(nitrate) inter-actions [2.667?(3) and 2.840?(3)?Å] result in a three-dimensional network. The water mol-ecule consolidates the network structure by forming hydrogen bonds, one to the polycationic chain and one to the nitrate anion.

SUBMITTER: Ma YT

PROVIDER: S-EPMC2915063 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[silver(I)-μ-N-(3-pyridyl-meth-yl)pyridine-4-carboxamide] nitrate monohydrate].

Ma Yu-Tao YT Zhao Qi-Hua QH

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

In the title compound, {[Ag(C(12)H(11)N(3)O)]NO(3)·H(2)O}(n), the Ag atom is coordinated by two N atoms from the heterocyclic ligand, giving a linear polycationic chain. Two long Ag⋯O(nitrate) inter-actions [2.667 (3) and 2.840 (3) Å] result in a three-dimensional network. The water mol-ecule consolidates the network structure by forming hydrogen bonds, one to the polycationic chain and one to the nitrate anion. ...[more]

PMID: 21200470

Similar Datasets

catena-Poly[[silver(I)-?-[N-(4-pyridyl-meth-yl)pyridine-4-carboxamide-?N:N']] nitrate monohydrate].

Project description:The title coordination polymer, {[Ag(C(12)H(11)N(3)O)]NO(3)·H(2)O}(n), has a polycationic chain motif in which the Ag atom is bridged by the heterocyclic ligand; the Ag atom shows linear coordination. If the two long Ag?O(nitrate) inter-actions [2.794?(6) and 2.867?(5)?Å] are regarded as bonds, the compound adopts a three-dimensional network structure. The water mol-ecule consolidates the network structure by forming hydrogen bonds, one to the polycationic chain and one to the nitrate anion.

| S-EPMC2960773 | biostudies-literature

Bis[4-(4-pyridyl-meth-oxy)phenol-κN]silver nitrate monohydrate.

Project description:In the title compound, [Ag(C(12)H(11)NO(2))(2)]NO(3)·H(2)O, the Ag(I) ion is coordinated by two N atoms from two different 4-(4-pyridyl-meth-oxy)phenol ligands, generating a nearly linear coordination geometry with an N-Ag-N angle of 167.1 (1)°. A three-dimensional supra-molecular network is built from the uncoordinated nitrate anion, the water mol-ecule and the cation through O-H⋯O hydrogen bonds.

| S-EPMC3007012 | biostudies-literature

catena-Poly[[silver(I)-μ-dipyrazin-2-ylamine] perchlorate monohydrate].

Project description:In the title complex, {[Ag(C(8)H(7)N(5))]ClO(4)·H(2)O}(n), the multidentate dipyrazin-2-ylamine acts as a μ(2)-bridging link with an anti-syn configuration, assembling the Ag(I) ions into a zigzag chain structure. The Ag(I) ion is linearly coordinated by two dipyrazin-2-ylamine ligands through two pyrazine N atoms. (ClO(4) (-))⋯π(pyrazine) [O⋯centroid distances of 3.612 (3) and 3.664 (1) Å] and π-π inter-actions [centroid-centroid distance = 3.518 (2) Å] as well as O-H⋯O and N-H⋯O hydrogen-bonds assemble the chains into a three-dimensional supra-molecular aggregation.

| S-EPMC2970971 | biostudies-literature

Crystal structure of catena-poly[[silver(I)-{μ-2,6-bis-[(1H-pyrazol-1-yl)meth-yl]pyridine-κ(3) N (1),N (2):N (2')}] nitrate].

Project description:In the title complex, {[Ag(C13H13N5)]NO3} n , the Ag(I) atom is coordinated by three N atoms from two bidentate/monodentate pyrazolylpyridyl ligands to form a distorted trigonal-planar geometry [range of angles: 83.34 (6) (chelate ring) to 139.15 (7) °]. The chelate ring has a distorted boat conformation. The dihedral angle between the pyridyl ring and the coordinating pyrazolyl ring is 67.22 (6)°. The non-coordinating pyrazolyl ring is twisted by 62.97 (7)° from the pyridyl ring. In the crystal, the complex cations are arranged in polymeric chains along the c-axis direction, with the nitrate counter-anions situated in between. Weak C-H⋯O hydrogen bonds link the ions into a three-dimensional network.

| S-EPMC4438834 | biostudies-literature

catena-Poly[[aquanickel(II)]-μ-pyridine-2,6-dicarboxylato-[aquanickel(II)]-μ-2,5-di-4-pyridyl-1,3,4-thiadiazole].

Project description:The two independent Ni(II) ions in the one-dimensional title complex, [Ni(2)(C(7)H(3)NO(4))(2)(C(12)H(8)N(4)S)(H(2)O)(2)](n) or [Ni(2)(pydc)(2)(bpt)(H(2)O)(2)](n) (H(2)pydc = pyridine-2,6-dicarboxylic acid and bpt = 2,5-di-4-pyrid-yl-1,3,4-thia-diazole), have different coordination environments. One Ni(II) ion is in a slightly-distorted octa-hedral coordination environment formed by three O atoms from two adjacent pydc ligands, two N atoms from bpt and pydc ligands, and one water mol-ecule, while the other Ni(II) ion is in distorted square-pyramidal geometry, coordinated by two O atoms from two carboxyl-ate groups and two N atoms from the pyridine rings of the pydc and bpt ligands in the basal plane, while a coordinated water mol-ecule occupies the apical site. In the crystal structure, the H atoms of both water mol-ecules are involved in inter-molecular hydrogen bonds with the O atoms of uncoordinated carboxyl-ate groups, which link chains into a three-dimensional network.

| S-EPMC2977561 | biostudies-literature

catena-Poly[[[aqua-silver(I)]-μ-4,4'-bipyridine-κN:N'] 4-amino-benzoate nitrate hydrate].

Project description:In the structure of the title compound, 2[Ag(C(10)H(8)N(2))(H(2)O)](C(7)H(6)NO(2))(NO(3))·H(2)O, the Ag(I) atom is three-coordinated in a T-shaped configuration by two N atoms from two symmetry-related 4,4'-bipyridine (bipy) ligands at short distances and by one water O atom at a longer distance. Each bipy ligand bridges two neighbouring Ag(I) atoms, forming a chain structure extending parallel to [101]. The complete 4-amino-benzoate anion, the nitrate anion and the uncoordinated water mol-ecule are located on mirror planes: together with the coordinated water mol-ecule, they form N-H⋯O, O-H⋯O and O-H⋯N hydrogen bonds, stabilizing the crystal structure.

| S-EPMC2983544 | biostudies-literature

catena-Poly[[tris[silver(I)-μ-4,4'-bi-pyridine-κN:N']] tris-(perchlorate) di-hydrate].

Project description:In the title compound, {[Ag(3)(C(10)H(8)N(2))(3)](ClO(4))(3)·2H(2)O}(n), one of the Ag(I) ions, one of the 4,4'-bipyridine (bipy) ligands and one of the perchlorate anions are each situated on a twofold rotation axis. Each Ag(I) ion is coordinated by two N atoms from two bridging bipy ligands, forming chains along [101]. π-π inter-actions between the pyridine rings [centroid-centroid distances = 3.638 (8) and 3.688 (8) Å] connect the chains. Inter-molecular O-H⋯O hydrogen bonds link the uncoord-inated water mol-ecules and the perchlorate anions.

| S-EPMC3246936 | biostudies-literature

catena-Poly[bis-(sulfamethoxazolium) [[trichloridocadmate(II)]-μ-chlorido] monohydrate].

Project description:In the title compound, {(C(10)H(12)N(3)O(3)S)(2)[CdCl(4)]·H(2)O}(n), the Cd(II) atom is five-coordinate with a distorted trigonal-bipyramidal geometry formed by chloride ions. The Cd atom and two of the Cl atoms lie on a mirror plane. The cation is protonated on the amino group N atom; it is not coordinated to cadmium, but is hydrogen bonded to the chlorido ligands. Each water mol-ecule bridges two chlorido ligands, generating ring motifs along the -Cd-Cl-Cd- chains. The isoxazole unit and the amide groups are linked through a pair of N-H⋯N hydrogen bonds. The crystal structure is stabilized by N-H⋯O, O-H⋯Cl, C-H⋯N, N-H⋯Cl and C-H⋯O hydrogen bonds.

| S-EPMC2915166 | biostudies-literature

catena-Poly[[[(1,10-phenanthroline-κN,N')zinc]-μ-pyridine-2,3-dicarboxyl-ato-κN,O:O,O] monohydrate].

Project description:In the title complex, {[Zn(C(7)H(3)NO(4))(C(12)H(8)N(2))]·H(2)O}(n), the Zn(II) ion is in a distorted octa-hedral environment, defined by two N atoms from a chelating 1,10-phenanthroline (phen) ligand and one N atom and three O atoms from two pyridine-2,3-dicarboxyl-ate (2,3-pydc) ligands. The bridging 2,3-pydc ligands connect the Zn(II) ions into a chain extending along [010]. O-H⋯O hydrogen bonds between the uncoordinated water mol-ecules and the uncoordinated carboxyl-ate O atoms, as well as π-π inter-actions between the pyridine rings of the phen ligands [centroid-centroid distance = 3.557 (2) Å], are observed.

| S-EPMC3152098 | biostudies-literature

catena-Poly[silver(I)-μ-pyrazolato-κN:N'].

Project description:The title compound, [Ag(C(3)H(3)N(2))](n), has an infinite helical chain structure in which each pyrazolate group bridges two Ag(I) atoms related by a 2(1) axis with an intra-chain Ag⋯Ag separation of 3.3718 (7) Å. Each Ag(I) center is linearly coordinated by two N atoms [N-Ag-N angle = 169.98 (14)°]. The chains are held together by inter-chain Ag⋯Ag inter-actions [3.2547 (6) Å], forming a two-dimensional layer. The X-ray single-crystal diffraction result is consonant with that of the ab initio X-ray powder diffraction reported by Masciocchi, Moret, Cairati, Sironi, Ardizzoia & La Monica [J. Am. Chem. Soc. (1994). 116, 7668-7676], with only minor deviations of structural parameters.

| S-EPMC2960218 | biostudies-literature

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