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Catena-Poly[[silver(I)-[?-4-(2-pyrid-yl)-pyrimidine-2-sulfonato]] monohydrate].

ABSTRACT: In the title compound, {[Ag(C(9)H(6)N(3)O(3)S)]·H(2)O}(n), the Ag(I) atom is coordinated by three N atoms and two sulfonate O atoms from two different 4-(2-pyrid-yl)pyrimidine-2-sulfonate ligands. The ligand bridges two Ag(I) atoms, forming a polymeric zigzag chain propagating parallel to [001]. The uncoordinated water mol-ecule is involved in hydrogen bonds with sulfonate O atoms.

SUBMITTER: Zhu HB

PROVIDER: S-EPMC2979118 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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catena-Poly[[silver(I)-[μ-4-(2-pyrid-yl)-pyrimidine-2-sulfonato]] monohydrate].

Zhu Hai-Bin HB

Acta crystallographica. Section E, Structure reports online 20100410 Pt 5

In the title compound, {[Ag(C(9)H(6)N(3)O(3)S)]·H(2)O}(n), the Ag(I) atom is coordinated by three N atoms and two sulfonate O atoms from two different 4-(2-pyrid-yl)pyrimidine-2-sulfonate ligands. The ligand bridges two Ag(I) atoms, forming a polymeric zigzag chain propagating parallel to [001]. The uncoordinated water mol-ecule is involved in hydrogen bonds with sulfonate O atoms. ...[more]

PMID: 21579011

Similar Datasets

Poly[aqua-bis-[?(3)-4-(3-pyrid-yl)pyrimidine-2-sulfonato-?N:N,O:O][?(2)-4-(3-pyrid-yl)pyrimidine-2-sulfonato-?N:N,O]tris-ilver(I)].

Project description:In the crystal structure of the title compound, [Ag(3)(C(9)H(6)N(3)O(3)S)(3)(H(2)O)(2)](n), the mol-ecules are linked into three-decked polymeric zigzag chains propagating in [100]. On the middle deck, the Ag atom is five-coordinated by three O atoms from three 4-(3-pyrid-yl)pyrimidine-2-sulfonate (L) ligands, one of which lies on a mirror plane with the sulfonate group disordered over two orientations in a 1:1 ratio, and two N atoms from two L ligands, which lie on the same mirror plane. On the upper and lower decks, the Ag atom is four-coordinated by an aqua ligand, one O and two N atoms from two L ligands with the pyridyl and pyrimidine rings twisted at 19.8?(2)°. In the polymeric chain, there are ?-? inter-actions between six-membered rings of L ligands from different decks with centroid-centroid distances of 3.621?(7) and 3.721?(3)?Å. In the crystal, inter-molecular O-H?O hydrogen bonds link further these three-decked chains into layers parallel to (010).

| S-EPMC3212147 | biostudies-literature

catena-Poly[[(p-toluene-sulfonato-?O)silver(I)]-?-1,3-bis-(pyridin-4-yl)propane-?(2)N:N'].

Project description:In the title compound, [Ag(C(7)H(7)O(3)S)(C(13)H(14)N(2))](n), the Ag(I) ion is coordinated in a T-shape by two N atoms from two symmetry-related 1,3-bis-(pyridin-4-yl)propane ligands and one O atom from a p-toluene-sulfonate ligand, forming a one-dimensional zigzag chain along [001]. In the crystal, weak C-H?O hydrogen bonds and weak Ag?Ag inter-actions [3.2628?(5)?Å] are observed.

| S-EPMC3344348 | biostudies-literature

Tetra-aqua-bis[4-(4-pyrid-yl)pyrimidine-2-sulfonato]copper(II) dihydrate.

Project description:In the title complex, [Cu(C(9)H(6)N(3)O(3)S)(2)(H(2)O)(4)]·2H(2)O, the Cu(II) atom lies on an inversion centre and is coordinated by four water mol-ecules in equatorial positions and two N atoms from two 4-(4-pyrid-yl)pyrimidine-2-sulfonate ligands in apical positions. The asymmetric unit contains half of the complex and one free water mol-ecule. The water mol-ecules, including the uncoordinated water mol-ecules, and sulfonate O atoms are involved in O-H⋯O and O-H⋯N hydrogen-bonding inter-actions.

| S-EPMC2977545 | biostudies-literature

catena-Poly[[silver(I)-μ-N-(3-pyridyl-meth-yl)pyridine-4-carboxamide] nitrate monohydrate].

Project description:In the title compound, {[Ag(C(12)H(11)N(3)O)]NO(3)·H(2)O}(n), the Ag atom is coordinated by two N atoms from the heterocyclic ligand, giving a linear polycationic chain. Two long Ag⋯O(nitrate) inter-actions [2.667 (3) and 2.840 (3) Å] result in a three-dimensional network. The water mol-ecule consolidates the network structure by forming hydrogen bonds, one to the polycationic chain and one to the nitrate anion.

| S-EPMC2915063 | biostudies-literature

catena-Poly[[aqua-[3-(3-pyrid-yl)acrylato]gadolinium(III)]-bis-[?-3-(3-pyrid-yl)acrylato]].

Project description:In the title compound, [Gd(C(8)H(6)NO(2))(3)(H(2)O)](n), the gadolinium(III) ion is coordinated by eight carboxyl-ate O atoms and one water mol-ecule. The carboxyl-ate ligands bridge pairs of gadolinium(III) ions, forming a zigzag chain along [100]. Hydrogen bonds link the chains into sheets parallel to (001).

| S-EPMC2961579 | biostudies-literature

catena-Poly[[silver(I)-?-[N-(4-pyridyl-meth-yl)pyridine-4-carboxamide-?N:N']] nitrate monohydrate].

Project description:The title coordination polymer, {[Ag(C(12)H(11)N(3)O)]NO(3)·H(2)O}(n), has a polycationic chain motif in which the Ag atom is bridged by the heterocyclic ligand; the Ag atom shows linear coordination. If the two long Ag?O(nitrate) inter-actions [2.794?(6) and 2.867?(5)?Å] are regarded as bonds, the compound adopts a three-dimensional network structure. The water mol-ecule consolidates the network structure by forming hydrogen bonds, one to the polycationic chain and one to the nitrate anion.

| S-EPMC2960773 | biostudies-literature

catena-Poly[[silver(I)-μ-dipyrazin-2-ylamine] perchlorate monohydrate].

Project description:In the title complex, {[Ag(C(8)H(7)N(5))]ClO(4)·H(2)O}(n), the multidentate dipyrazin-2-ylamine acts as a μ(2)-bridging link with an anti-syn configuration, assembling the Ag(I) ions into a zigzag chain structure. The Ag(I) ion is linearly coordinated by two dipyrazin-2-ylamine ligands through two pyrazine N atoms. (ClO(4) (-))⋯π(pyrazine) [O⋯centroid distances of 3.612 (3) and 3.664 (1) Å] and π-π inter-actions [centroid-centroid distance = 3.518 (2) Å] as well as O-H⋯O and N-H⋯O hydrogen-bonds assemble the chains into a three-dimensional supra-molecular aggregation.

| S-EPMC2970971 | biostudies-literature

catena-Poly[[dibromidozinc(II)]-?-4-(3-pyrid-yl)-4H-1,2,4-triazole].

Project description:The title complex, [ZnBr(2)(C(7)H(6)N(4))](n), was formed under hydro-thermal conditions using the ligand 4-(3-pyrid-yl)-4H-1,2,4-triazole (L). The unique Zn(II) ion is coordinated by one triazole N atom, one pyridine N atom and two Br atoms in a slightly distorted tetra-hedral coordination environment. Symmetry-related Zn(II) ions are connected by bridging L ligands into chains parallel to [001] in which the Zn?Zn separation is 8.643?(7)?Å. In the crystal structure, weak inter-molecular C-H?Br hydrogen bonds link the chains into a three-dimensional network.

| S-EPMC3007524 | biostudies-literature

catena-Poly[[dianilinedichloridocopper(II)]-?(2)-2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole].

Project description:In the title compound, [CuCl(2)(C(6)H(7)N)(2)(C(12)H(8)N(4)O)](n), the Cu atom, located on an inversion center, is coordinated by four N atoms from two aniline ligands and two 2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole ligands. Two Cl atoms lying above and below the plane formed by these four N atoms inter-act weakly with the Cu atom [Cu-Cl = 2.7870?(7)?Å]. The trans 2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole ligands act as bridging ligands, linking adjacent Cu atoms and forming a one-dimensional coordination polymer. Two anilines coordinate with each Cu atom as terminal groups. The structure contains two classical N-H?Cl and two non-classical C-H?Cl hydrogen bonds.

| S-EPMC2980127 | biostudies-literature

catena-Poly[[[[3-(2-pyrid-yl)-1H-pyrazole]manganese(II)]-?-oxalato] sesquihydrate].

Project description:In the title compound, {[Mn(C(2)O(4))(C(8)H(7)N(3))]·1.5H(2)O}(n), the Mn(II) ion is chelated by two O,O'-bidentate oxalate ions and an N,N'-bidentate 3-(2-pyrid-yl)pyrazole mol-ecule, resulting in a distorted cis-MnN(2)O(4) octa-hedral geometry for the metal ion. The bridging oxalate ions generate wave-like polymeric chains propagating in [001]. The packing is consolidated by N-H?O and O-H?O hydrogen bonds. One of the water O atoms lies on a crystallographic twofold axis.

| S-EPMC2971254 | biostudies-literature

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