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Bis{2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolato-?N,O}cobalt(II).

ABSTRACT: In the title compound, [Co(C(14)H(10)Br(2)NO)(2)], the Co(II) ion is coordinated by an O and an N atom from two equivalent 2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolate ligands, displaying a distorted tetra-hedral geometry. The Co(II) ion occupies a special position on a twofold rotation axis and thus the mol-ecular symmetry of the complex is C(2). The two phenolate rings are perpendicular [89.8?(3)°].

SUBMITTER: Jiang W

PROVIDER: S-EPMC2959770 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Bis{2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolato-κN,O}cobalt(II).

Jiang Wei W Mo Gui-Di GD Jin Lie L

Acta crystallographica. Section E, Structure reports online 20081015 Pt 11

In the title compound, [Co(C(14)H(10)Br(2)NO)(2)], the Co(II) ion is coordinated by an O and an N atom from two equivalent 2-[(E)-benzyl-imino-meth-yl]-4,6-dibromo-phenolate ligands, displaying a distorted tetra-hedral geometry. The Co(II) ion occupies a special position on a twofold rotation axis and thus the mol-ecular symmetry of the complex is C(2). The two phenolate rings are perpendicular [89.8 (3)°]. ...[more]

PMID: 21580845

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(E)-2-(Benzyl-imino-meth-yl)-4,6-dibromo-phenol.

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Bis{2-[(E)-benzyl-imino-meth-yl]-4-methyl-phen-olato-κN,O}cobalt(II).

Project description:In the title complex, [Co(C(15)H(14)NO)(2)], the Co(II) atom, situated on an inversion centre, is coordinated by two O and two N atoms from two symmetry-related bidentate Schiff base ligands in a slightly distorted square-planar geometry. The two phenolate rings form a dihedral angle of 10.53 (2)°.

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