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Bis[?-2-(benzyl-imino-meth-yl)-4-chloro-phenolato]bis[chloridocopper(II)].

ABSTRACT: The title complex, [Cu(2)(C(14)H(11)ClNO)(2)Cl(2)], has a centrosymmetric dinuclear structure where two symmetry-related copper(II) metal centres are bridged by the O atoms of two phen-oxy groups. Each copper(II) centre displays a distorted tetra-hedral coordination provided by one N atom and two O atoms from two Schiff base ligands and by one Cl atom. The Cu?Cu separation is 3.0702?(9)?Å.

SUBMITTER: Pu X

PROVIDER: S-EPMC2915143 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Bis[μ-2-(benzyl-imino-meth-yl)-4-chloro-phenolato]bis[chloridocopper(II)].

Pu Xiaohua X Zhang Xinli X Li Zongxiao Z

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

The title complex, [Cu(2)(C(14)H(11)ClNO)(2)Cl(2)], has a centrosymmetric dinuclear structure where two symmetry-related copper(II) metal centres are bridged by the O atoms of two phen-oxy groups. Each copper(II) centre displays a distorted tetra-hedral coordination provided by one N atom and two O atoms from two Schiff base ligands and by one Cl atom. The Cu⋯Cu separation is 3.0702 (9) Å. ...[more]

PMID: 21200563

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