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Tris[4-(2-pyridylmethyl-eneamino)phenol]iron(II) bis-(perchlorate).

ABSTRACT: In the title compound, [Fe(C(12)H(10)N(2)O)(3)](ClO(4))(2), the metal center is coordinated by six N atoms from the three bidentate chelating ligands in a distorted octa-hedral coordination geometry, with overall formation of the meridional (OC-6-21) isomer. Inter-molecular O-H?O hydrogen bonds between the hydroxyl groups of the cation and the counter-anions form an infinite one-dimensional chain in the c-axis direction.

SUBMITTER: Serb MD

PROVIDER: S-EPMC2915141 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Tris[4-(2-pyridylmethyl-eneamino)phenol]iron(II) bis-(perchlorate).

Serb Mihaela-Diana MD Calmuschi-Cula Beatrice B Dumitru Florina F Englert Ulli U Guran Cornelia C

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

In the title compound, [Fe(C(12)H(10)N(2)O)(3)](ClO(4))(2), the metal center is coordinated by six N atoms from the three bidentate chelating ligands in a distorted octa-hedral coordination geometry, with overall formation of the meridional (OC-6-21) isomer. Inter-molecular O-H⋯O hydrogen bonds between the hydroxyl groups of the cation and the counter-anions form an infinite one-dimensional chain in the c-axis direction. ...[more]

PMID: 21200560

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