Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato-?N,N',O]zinc(II) dihydrate.

ABSTRACT: In the title complex, [Zn(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, the Zn(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms and two O atoms from two tridentate 2-(2-pyridylmethyl-eneamino)benzene-sulfonate ligands in a slightly distorted octa-hedral environment. In the crystal structure, the complex forms a two-dimensional network through inter-molecular O-H?O and C-H?O hydrogen bonds.

SUBMITTER: Cai CX

PROVIDER: S-EPMC2960510 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato-κN,N',O]zinc(II) dihydrate.

Cai Cheng-Xiang CX Ou-Yang Miao M Zhao Zhi-Yuan ZY Jiang Yi-Min YM

Acta crystallographica. Section E, Structure reports online 20080823 Pt 9

In the title complex, [Zn(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, the Zn(II) ion lies on a crystallographic inversion center and is coordinated by four N atoms and two O atoms from two tridentate 2-(2-pyridylmethyl-eneamino)benzene-sulfonate ligands in a slightly distorted octa-hedral environment. In the crystal structure, the complex forms a two-dimensional network through inter-molecular O-H⋯O and C-H⋯O hydrogen bonds. ...[more]

PMID: 21201634

Similar Datasets

Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato-?N,N',O]cobalt(II) dihydrate.

Project description:The title complex, [Co(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, has site symmetry 2 with the Co(II) cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyl-eneamino)benzene-sulfonate (paba) ligands chelate to the Co(II) cation in a distorted octa-hedral geometry. The pyridine and benzene rings in the paba ligand are oriented at a dihedral angle of 42.86?(13)°. Inter-molecular O-H?O and C-H?O hydrogen bonding is present in the crystal structure.

| S-EPMC2971130 | biostudies-literature

Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato-κN,N',O]cadmium(II) dihydrate.

Project description:The title complex, [Cd(Paba)(2)]·2H(2)O or [Cd(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, was synthesized by the reaction of the potassium salt of 2-(2-pyridylmethyl-eneamino)benzene-sulfonic acid (PabaK) with CdCl(2)·2.5H(2)O in methanol. The Cd(II) atom lies on a crystallographic twofold axis and is coordinated by four N atoms and two O atoms from two deprotonated tridentate 2-(2-pyridylmethyl-eneamino)benzene-sulfonate ligands in a slightly distorted octa-hedral environment. There are extensive hydrogen bonds of the type O-H⋯O between the uncoordinated water molecules and the sulfonate O atoms, through which the complex forms a layered structure parallel to (001).

| S-EPMC2959732 | biostudies-literature

Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato-?N,N',O]manganese(II) dihydrate.

Project description:The title complex, [Mn(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, is isotypic with the previously reported Zn(II) and Cd(II) species. The complex was prepared by the reaction of the potassium salt of 2-(2-pyridylmethyl-eneamino)benzene-sulfonic acid with MnCl(2)·6H(2)O in methanol. The complex displays twofold symmetry, with the ligands coordinated in a tridentate meridional-like arrangement through pyridyl N, imine N, and sulfonate O atoms. The metal center has a strongly distorted octa-hedral coordination geometry. The uncoordin-ated water mol-ecules and the complexes participate in a hydrogen-bonding network, forming a two-dimensional structure parallel to the ab plane.

| S-EPMC2969898 | biostudies-other

Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato]-?N,N',O;?N,N'-copper(II).

Project description:In the mononuclear title compound, [Cu(C(12)H(9)N(2)O(3)S)(2)], the copper(II) salt of 2-(2-pyridylmethyl-eneamino)benzene-sulfonic acid, the Cu(II) atom is coordinated by one O and two N atoms from a monoanion as well as by two N atoms from another monoanion in a distorted trigonal-bipyramidal environment.

| S-EPMC2970261 | biostudies-literature

1,4-Bis(3-pyridylmethyl-eneamino-meth-yl)benzene.

Project description:The title compound, C(20)H(18)N(4), is a flexible 3,3'-bipyridyl-type ligand with a long spacer group between the two pyridyl functions. The mol-ecule crystallizes around an inversion center, with one half-mol-ecule in the asymmetric unit and a dihedral angle of 71.85?(8)° between the pyridine ring and the central benzene ring.

| S-EPMC2968309 | biostudies-literature

Bis[2-(2-pyridylmethyl-amino)ethane-sulfonato-?N,N',O]zinc(II).

Project description:The title mononuclear complex, [Zn(C(8)H(11)N(2)O(3)S)(2)], is a zinc salt of 2-(2-pyridylmethyl-amino)ethane-sulfonic acid (Hpmt). The Zn(II) ion is located on an inversion centre and is octahedrally surrounded by four N and two O atoms. The deprotonated pmt(-) anion coordinates in a facial arrangement through its two N atoms and one of the sulfonate O atoms. The crystal packing is determined by inter-molecular N-H?O and C-H?O hydrogen bonds.

| S-EPMC2969410 | biostudies-literature

2,3,5,6-Tetra-fluoro-1,4-bis-(2-pyridylmethyl-eneamino-meth-yl)benzene.

Project description:The title compound, C(20)H(14)F(4)N(4), is a flexible bis-pyridine-type ligand with an extended fluorinated spacer group between the two pyridyl functions. The centroid of the central aromatic ring is situated on a crystallographic center of inversion. The dihedral angle between the pyridine ring and the central benzene ring is 63.85?(9)°. The crystal structure exhibits inter-molecular C-H?F hydrogen-bonding inter-actions.

| S-EPMC2968251 | biostudies-literature

Bis(4-amino-benzene-sulfonato-?N)diaqua-bis(dimethyl-formamide-?O)nickel(II) dihydrate.

Project description:In the title compound, [Ni(C(6)H(6)NO(3)S)(2)(C(3)H(7)NO)(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion (site symmetry ) is coordinated by two -NH(2) groups from two 4-amino-benzene-sulfonate anions, two O atoms from two dimethyl-formamide mol-ecules and two water mol-ecules, forming a slightly distorted trans-NiN(2)O(4) octa-hedral geometry. In the crystal structure, inter-molecular O-H?O, O-H?(O,O) and N-H?O hydrogen bonds link the components into a three-dimensional network. The O atoms of the sulfonate group are disordered over two sets of sites in a 0.833?(4):0.167?(4) ratio and the O atom of the uncoordinated water mol-ecule is disordered over two sites in a 0.637?(18):0.363?(18) ratio.

| S-EPMC2969510 | biostudies-literature

Bis(4-amino-benzene-sulfonato-?O)bis-(propane-1,3-diamine-?N,N')copper(II) dihydrate.

Project description:In the title compound, [Cu(C(3)H(10)N(2))(2)(C(6)H(6)NO(3)S)(2)]·2H(2)O, the Cu(II) atom lies on an inversion center and is hexa-coordinated by four N atoms from two 1,3-diamino-propane ligands and two O atoms from two 4-amino-benzene-sulfonate ligands in a trans arrangement, displaying a distorted and axially elongated octa-hedral coordination geometry, with the O atoms at the axial positions. A three-dimensional network is formed in the crystal structure through O-H?O, N-H?O and N-H?N hydrogen bonds.

| S-EPMC2972104 | biostudies-literature

Hexaaqua-zinc(II) bis-(4-hydroxy-benzene-sulfonate) dihydrate.

Project description:In the crystal structure of the title compound, [Zn(H(2)O)(6)](C(6)H(5)O(4)S)(2)·2H(2)O, the Zn(II) atom lies on a center of inversion. The complex cation inter-acts with the anion and uncoord-inated water mol-ecules by O-H?O hydrogen bonds, generating a three-dimensional network. The anion is disordered over two equal positions along the hydr-oxy-sulfonate C-C axis.

| S-EPMC2971186 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data