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Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato-?N,N',O]cobalt(II) dihydrate.

ABSTRACT: The title complex, [Co(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, has site symmetry 2 with the Co(II) cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyl-eneamino)benzene-sulfonate (paba) ligands chelate to the Co(II) cation in a distorted octa-hedral geometry. The pyridine and benzene rings in the paba ligand are oriented at a dihedral angle of 42.86?(13)°. Inter-molecular O-H?O and C-H?O hydrogen bonding is present in the crystal structure.

SUBMITTER: Huang XR 

PROVIDER: S-EPMC2971130 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Bis[2-(2-pyridylmethyl-eneamino)benzene-sulfonato-κN,N',O]cobalt(II) dihydrate.

Huang Xue-Ren XR   Ou-Yang Miao M   Yang Ge-Ge GG   Meng Xiu-Jin XJ   Jiang Yi-Min YM  

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

The title complex, [Co(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, has site symmetry 2 with the Co(II) cation located on a twofold rotation axis. Two tridentate 2-(2-pyridylmethyl-eneamino)benzene-sulfonate (paba) ligands chelate to the Co(II) cation in a distorted octa-hedral geometry. The pyridine and benzene rings in the paba ligand are oriented at a dihedral angle of 42.86 (13)°. Inter-molecular O-H⋯O and C-H⋯O hydrogen bonding is present in the crystal structure. ...[more]

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