Unknown

Dataset Information

0

Chlorido{?-2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolato}-?-oxido-dicopper(II) trihydrate.

ABSTRACT: In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N',O-chelated by one arm of the 2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex. One of the Cu(II) cations is further coordinated by an Cl(-) anion in the apical direction. In the crystal, lattice water mol-ecules are linked with the complex mol-ecule via O-H?Cl hydrogen bonds while O-H?O hydrogen bonding occurs between lattice water mol-ecules , forming three-dimensional network structure.

SUBMITTER: Zhou JJ 

PROVIDER: S-EPMC3379123 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Chlorido{μ-2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolato}-μ-oxido-dicopper(II) trihydrate.

Zhou Jing-Jing JJ   Xiao Wei W   Mao Jia-Wei JW   Zhou Hong H  

Acta crystallographica. Section E, Structure reports online 20120526 Pt 6

In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N',O-chelated by one arm of the 2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex. One of the Cu(II) cations is further coordinated by an Cl(-) anion in the apical dire  ...[more]

Similar Datasets

Unknown {4-Chloro-2-[(2-hy-droxy-eth-yl)imino-meth-yl]phenolato}{4-chloro-2-[(2-oxido-eth-yl)imino-meth-yl]phenolato}cobalt(III).
| S-EPMC3008055 | biostudies-literature
Unknown Chlorido(2-{1-[(2-morpholino-eth-yl)imino]-eth-yl}phenolato-?N,N',O)copper(II).
| S-EPMC3050288 | biostudies-literature
Unknown Chlorido{4-chloro-2-[(2-morpholinoeth-yl)imino-meth-yl]phenolato-κN,N',O}copper(II).
| S-EPMC2977511 | biostudies-literature
Unknown Bis{4-chloro-2-[(2-hy-droxy-eth-yl)imino-meth-yl]phenolato}nickel(II) monohydrate.
| S-EPMC3200802 | biostudies-literature
Unknown Chlorido[4-chloro-2-(pyridin-2-yl-methyl-imino-meth-yl)phenolato-?(3)N,N',O]copper(II).
| S-EPMC3344299 | biostudies-literature
Unknown 2,6-Bis[1-(2,6-diethyl-phenyl-imino)eth-yl]pyridine.
| S-EPMC2959797 | biostudies-literature
Unknown Bis{2-[1-(benzyl-imino)-eth-yl]phenolato}palladium(II).
| S-EPMC3007840 | biostudies-literature
Unknown (E)-2,4-Dichloro-6-{1-[(2-chloro-eth-yl)imino]-eth-yl}phenol.
| S-EPMC3011393 | biostudies-literature
Unknown Bis[2-(1-imino-eth-yl)phenolato-?N,O]nickel(II).
| S-EPMC3254291 | biostudies-literature
Unknown Bis{2-bromo-4-chloro-6-[(E)-(2,6-di-methyl-phen-yl)imino-meth-yl]phenolato-?(2) N,O}cobalt(II).
| S-EPMC3588491 | biostudies-literature