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Aqua-(3-methyl-isoquinoline-?N)silver(I) 4-amino-benzene-sulfonate.

ABSTRACT: In the title compound, [Ag(C(10)H(9)N)(H(2)O)](C(6)H(6)NO(3)S), the Ag(I) atom is two-coordinated by one N atom from a 3-methyl-isoquinoline ligand and one water mol-ecule. The 4-amino-benzene-sulfonate counter-anion does not show any bonding inter-actions with the Ag(I) atom. The compound exhibits a three-dimensional supra-molecular structure constructed by hydrogen bonds. Adjacent isoquinoline groups form ?-? inter-actions, with a centroid-centroid distance of 3.54?(1)?Å. The crystal studied was an inversion twin.

SUBMITTER: Zhang YM

PROVIDER: S-EPMC2915149 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Aqua-(3-methyl-isoquinoline-κN)silver(I) 4-amino-benzene-sulfonate.

Zhang Yong-Mei YM Hou Dong-Yan DY Li Tie-Chun TC Xin Guang G

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

In the title compound, [Ag(C(10)H(9)N)(H(2)O)](C(6)H(6)NO(3)S), the Ag(I) atom is two-coordinated by one N atom from a 3-methyl-isoquinoline ligand and one water mol-ecule. The 4-amino-benzene-sulfonate counter-anion does not show any bonding inter-actions with the Ag(I) atom. The compound exhibits a three-dimensional supra-molecular structure constructed by hydrogen bonds. Adjacent isoquinoline groups form π-π inter-actions, with a centroid-centroid distance of 3.54 (1) Å. The crystal studied w ...[more]

PMID: 21200570

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