Browse
Submit Data
Databases
API
Help

Dataset Information

11 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(2-Amino-5-chloro-benzene-sulfonato-?O)bis-(3-methyl-isoquinoline-?N)silver(I).

ABSTRACT: The title compound, [Ag(C(6)H(5)ClNO(3)S)(C(10)H(9)N)(2)], crystallizes with two independent mol-ecules in the asymmetric unit. The Ag(+) cation is three-coordinated by one O atom from the 2-amino-5-chloro-benzene-sulfonate anion and two N atoms from two different 3-methyl-isoquinoline ligands in a slightly distorted trigonal-planar geometry. In the crystal, network of inter-molecular N-H?O hydrogen-bonding inter-actions generates a chain along [100].

SUBMITTER: Liu Q

PROVIDER: S-EPMC2984077 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(2-Amino-5-chloro-benzene-sulfonato-κO)bis-(3-methyl-isoquinoline-κN)silver(I).

Liu Qiang Q Feng Li L Li Yu-Jie YJ Dong Xian-Wu XW

Acta crystallographica. Section E, Structure reports online 20100317 Pt 4

The title compound, [Ag(C(6)H(5)ClNO(3)S)(C(10)H(9)N)(2)], crystallizes with two independent mol-ecules in the asymmetric unit. The Ag(+) cation is three-coordinated by one O atom from the 2-amino-5-chloro-benzene-sulfonate anion and two N atoms from two different 3-methyl-isoquinoline ligands in a slightly distorted trigonal-planar geometry. In the crystal, network of inter-molecular N-H⋯O hydrogen-bonding inter-actions generates a chain along [100]. ...[more]

PMID: 21580513

Similar Datasets

(2-Amino-5-chloro-benzene-sulfonato)bis-(triphenyl-phosphine)silver(I).

Project description:The asymmetric unit of the title mononuclear compound, [Ag(C(6)H(5)ClNO(3)S)(C(18)H(15)P)(2)], contains four independent mol-ecules. In each of the mol-ecules, the Ag(I) cation is three-coordinated by two triphenyl-phosphine ligands, and one N atom from a 2-amino-5-chloro-benzene-sulfonate anion. The mol-ecules are linked into a one-dimensional supra-molecular structure by N-H?O hydrogen bonds.

| S-EPMC2960176 | biostudies-literature

Bis(2-{[bis-(dimethyl-amino)-methyl-idene]amino-?N}benzene-sulfonato-?N)copper(II).

Project description:The mol-ecular structure of the title compound, [Cu(C11H16N3O3S)2], shows the Cu(II) atom with a distorted square-planar coordination geometry from the N2O2 donor set of the two chelating 2-{[bis-(dimethyl-amino)-methyl-idene]amino}-benzene-sulfonate ligands. The Cu(II) atom lies 0.065?(1)?Å above the N2O2 plane and the Cu-O [2 × 1.945?(2)?Å] and Cu-N bond lengths [1.968?(3) and 1.962?(3)?Å] lie in expected ranges. The two aromatic ring planes make a dihedral angle of 85.48?(1)°.

| S-EPMC3588740 | biostudies-literature

Aqua-(3-methyl-isoquinoline-?N)silver(I) 4-amino-benzene-sulfonate.

Project description:In the title compound, [Ag(C(10)H(9)N)(H(2)O)](C(6)H(6)NO(3)S), the Ag(I) atom is two-coordinated by one N atom from a 3-methyl-isoquinoline ligand and one water mol-ecule. The 4-amino-benzene-sulfonate counter-anion does not show any bonding inter-actions with the Ag(I) atom. The compound exhibits a three-dimensional supra-molecular structure constructed by hydrogen bonds. Adjacent isoquinoline groups form ?-? inter-actions, with a centroid-centroid distance of 3.54?(1)?Å. The crystal studied was an inversion twin.

| S-EPMC2915149 | biostudies-literature

Di-?-aqua-bis-{diaqua-[?-4-({4-[bis-(2-hy-droxy-eth-yl)amino]-6-chloro-1,3,5-triazin-2-yl}amino)-benzene-sulfonato]-sodium(I)}.

Project description:In the dinuclear title compound, [Na(2)(C(13)H(15)ClN(5)O(5)S)(2)(H(2)O)(6)](n), two Na(+) cations, disposed about a centre of inversion, are linked by two bridging water mol-ecules. The coordination geometry is based on an O(5) donor set defined by four water mol-ecules and a 4-amino-benzene-sulfonate O atom in a distorted trigonal-bipyramidal geometry. In the crystal, significant O-H?O, O-H?N and N-H?O hydrogen bonds lead to the formation of a three-dimensional architecture.

| S-EPMC3379186 | biostudies-literature

Diaqua-bis-{4-[(pyridin-2-yl)methyl-idene-amino]-benzene-sulfonato-?(2)N,N'}nickel(II) tetra-hydrate.

Project description:In the title complex, [Ni(C(12)H(9)N(2)O(3)S)(2)(H(2)O)(2)]·4H(2)O, the Ni(II) ion is coordinated by four N atoms from two bidentate chelating 4-[(pyridin-2-yl)methyl-idene-amino]-benzene-sulfonate ligands and two O atoms from cis-related water mol-ecules in a slightly distorted octa-hedral environment [Ni-N = 2.071?(3)-2.121?(3)?Å and Ni-O = 2.071?(2) and 2.073?(3)?Å]. In the crystal, the coordinated water mol-ecules and the four water mol-ecules of solvation are involved in inter-molecular O-H?O hydrogen-bonding inter-actions with water and sulfon-ate O-atom acceptors, giving a three-dimensional framework structure.

| S-EPMC3379134 | biostudies-literature

Bis(4-amino-benzene-sulfonato-?N)diaqua-bis(dimethyl-formamide-?O)nickel(II) dihydrate.

Project description:In the title compound, [Ni(C(6)H(6)NO(3)S)(2)(C(3)H(7)NO)(2)(H(2)O)(2)]·2H(2)O, the Ni(II) ion (site symmetry ) is coordinated by two -NH(2) groups from two 4-amino-benzene-sulfonate anions, two O atoms from two dimethyl-formamide mol-ecules and two water mol-ecules, forming a slightly distorted trans-NiN(2)O(4) octa-hedral geometry. In the crystal structure, inter-molecular O-H?O, O-H?(O,O) and N-H?O hydrogen bonds link the components into a three-dimensional network. The O atoms of the sulfonate group are disordered over two sets of sites in a 0.833?(4):0.167?(4) ratio and the O atom of the uncoordinated water mol-ecule is disordered over two sites in a 0.637?(18):0.363?(18) ratio.

| S-EPMC2969510 | biostudies-literature

Tetra-aqua-bis[2-(thio-semi-carbazono-methyl)benzene-sulfonato]manganese(II).

Project description:In the title compound, [Mn(C(8)H(8)N(3)O(3)S(2))(2)(H(2)O)(4)], the Mn(II) atom (site symmetry ) adopts a slightly distorted octa-hedral MnO(6) geometry. The mol-ecular conformation is supported by N-H?N and O-H?O hydrogen bonds. In the crystal, mol-ecules inter-act by O-H?O, O-H?S, N-H?O and N-H?S hydrogen bonds, thereby forming (011) sheets.

| S-EPMC2971282 | biostudies-literature

Bis(4-amino-benzene-sulfonato-?O)bis-(propane-1,3-diamine-?N,N')copper(II) dihydrate.

Project description:In the title compound, [Cu(C(3)H(10)N(2))(2)(C(6)H(6)NO(3)S)(2)]·2H(2)O, the Cu(II) atom lies on an inversion center and is hexa-coordinated by four N atoms from two 1,3-diamino-propane ligands and two O atoms from two 4-amino-benzene-sulfonate ligands in a trans arrangement, displaying a distorted and axially elongated octa-hedral coordination geometry, with the O atoms at the axial positions. A three-dimensional network is formed in the crystal structure through O-H?O, N-H?O and N-H?N hydrogen bonds.

| S-EPMC2972104 | biostudies-literature

Penta-aqua-bis[4-(2-hydroxy-benzyl-idene-amino)benzene-sulfonato]lead(II).

Project description:In the structure of the title compound, [Pb(C(13)H(10)NO(4)S)(2)(H(2)O)(5)], two S-O bonds and one C-N bond have lengths of 1.421?(9), 1.425?(8) and 1.268?(11)?Å, respectively, which suggests they are double bonds. Mol-ecules form a two-dimensional layered structure via O-H?O and O-H?N inter-actions. The Pb atom adopts distorted cubo-octahedral coordination.

| S-EPMC2968621 | biostudies-literature

(4-Amino-3-methyl-benzene-sulfonato)tri-?-aqua-penta-aqua-disodium 4-amino-3-methyl-benzene-sulfonate.

Project description:In the title compound, [Na(2)(C(7)H(8)NO(3)S)(H(2)O)(8)](C(7)H(8)NO(3)S), one Na(+) ion is bonded to six water mol-ecules in a distorted octa-hedral arrangement while the other is bonded to five water mol-ecules and one O atom of a 4-amino-3-methyl-benzene-sulfonate anion, also yielding a distorted NaO(6) octa-hedron. Three of the water molecules bridge the metal ions and an intra-molecular O-H?O hydrogen bond helps to establish the conformation. In the crystal, the component species inter-act by way of O-H?O, O-H?N and N-H?O hydrogen bonds.

| S-EPMC2979835 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data