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2-Amino-4-(4-bromo-phen-yl)-6-ferro-cenyl-pyridine-3-carbonitrile.

ABSTRACT: The title compound, [Fe(C(5)H(5))(C(17)H(11)BrN(3))], was synthesized by the reaction of 4-bromo-benzaldehyde, acetyl-ferrocene and ammonium acetate in an aqueous medium. The crystal packing is stabilized by inter-molecular N-H⋯N hydrogen bonds. The dihedral angles between the phenyl ring and the pyridine and cyclopentadienyl rings are 51.67 (13) and 12.12 (21)°, respectively.

SUBMITTER: Jia RH

PROVIDER: S-EPMC2924174 | biostudies-literature |

REPOSITORIES: biostudies-literature

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2-Amino-4-(4-chloro-phen-yl)-6-ferro-cenylpyridine-3-carbonitrile.

Project description:In the mol-ecule of the title compound, [Fe(C(5)H(5))(C(17)H(11)ClN(3))], the dihedral angles between the two five-membered rings and between the two six-membered rings are 3.28 (4) and 51.33 (4)°, respectively. In the crystal structure, inter-molecular N-H⋯N hydrogen bonds link the mol-ecules into centrosymmetric dimers.

| S-EPMC2961127 | biostudies-literature

2-Amino-4-(4-fluoro-phen-yl)-6-(naphthalen-1-yl)pyridine-3-carbonitrile.

Project description:The title compound, C(22)H(14)FN(3), was prepared by a one-pot condensation using malononitrile, an aromatic aldehyde, a methyl ketone and ammonium acetate as reacta-nts under microwave irradiation. The pyridine ring is twisted with respect to the benzene ring and the naphthalene ring system, making dihedral angles of 41.9?(1) and 45.2?(1)°, respectively. In the crystal, mol-ecules are connected via inter-molecular N-H?N and C-H?F hydrogen bonds, forming a three-dimensional network.

| S-EPMC3050308 | biostudies-literature

2-Amino-4-(3-fluoro-phen-yl)-6-(naphthalen-1-yl)pyridine-3-carbonitrile.

Project description:There are two independent mol-ecules in the asymmetric unit of the title compound, C(22)H(14)FN(3), which differ slightly in the relative orientations of the naphthyl and phenyl groups with respect to the pyridyl ring framework. In one mol-ecule, the naphthyl ring system and the phenyl ring form dihedral of angles 56.50?(2) and 48.23?(3)°, respectively, with the pyridyl ring plane. In the other mol-ecule, the corresponding dihedral angles are 50.01?(2) and 51.1?(3)°, respectively. In the crystal, inter-molecular N-H?N hydrogen bonds connect the independent mol-ecules into dimers.

| S-EPMC3011742 | biostudies-literature

2-Amino-4-(2-chloro-phen-yl)-6-(naph-thalen-1-yl)pyridine-3-carbonitrile.

Project description:In the title compound, C(22)H(14)ClN(3), prepared by a one-pot reaction under microwave irradiation, the dihedral angles between the central pyridine ring and the pendant naphthyl and chloro-benzene ring systems are 49.2?(2) and 58.2?(3)°, respectively. In the crystal, inversion dimers linked by pairs of N-H?N hydrogen bonds generate R(2) (2)(8) loops. The pyridine N atom is the acceptor.

| S-EPMC3379409 | biostudies-literature

2-Amino-4-(4-chloro-phen-yl)-4H-chromeno[8,7-b]pyridine-3-carbonitrile.

Project description:The asymmetric unit of the title compound, C19H12ClN3O, contains two mol-ecules with similar conformations. The 14 non-H atoms comprising the 4H-chromeno[8,7-b]pyridine residue are essentially coplanar (r.m.s. deviations = 0.037 and 0.042?Å for the two mol-ecules) and the main difference between them is seen in the twist about the bond linking the main residue to the attached chloro-benzene rings [dihedral angles = 79.01?(12) and 76.22?(11)° for the two mol-ecules]. Zigzag supra-molecular chains along the a-axis direction mediated by amino-pyridine N-H?N hydrogen bonds feature in the crystal packing; these are connected into a three-dimensional architecture by C-H?? inter-actions and Cl?Cl contacts [Cl?Cl = 3.3896?(14)?Å].

| S-EPMC3629505 | biostudies-literature

4-(4-Bromo-phen-yl)-2,6-diphenyl-pyridine.

Project description:In the title compound, C(23)H(16)BrN, the three benzene rings show a disrotatory counter-rotating arrangement around the central pyridine ring and are twisted with respect to the pyridine ring with dihedral angles of 19.56?(13), 27.54?(13) and 30.51?(13)°.

| S-EPMC2972060 | biostudies-literature

6-Amino-3-methyl-4-(4-nitro-phen-yl)-1-phenyl-pyrazolo[3,4-b]pyridine-5-carbonitrile.

Project description:The title compound, C(20)H(14)N(6)O(2), contains four rings. The dihedral angle between the pyridine ring and the pyrazole ring is 1.9 (1)°, i.e. almost coplanar, which gives rise to a conjugated structure. The dihedral angle between the nitro-substituted phenyl ring and the pyridine ring is 76.3 (1)° and that between the pyrazole ring and the non-substituted phenyl ring is 40.5 (1)°. In the crystal structure, symmetry-related mol-ecules are linked by N-H⋯O and C-H⋯N hydrogen bonds.

| S-EPMC2961049 | biostudies-literature

1-(4-Bromo-phen-yl)-2-methyl-1H-indole-3-carbonitrile.

Project description:In the title compound, C(16)H(11)BrN(2), the dihedral angle between the indole ring system and the phenyl ring is 58.85 (11)°.

| S-EPMC3200589 | biostudies-literature

4-(4-Bromo-phen-yl)-6-(1H-indol-3-yl)-2,2'-bipyridine-5-carbonitrile.

Project description:In the title compound, C(25)H(15)BrN(4), the two pyridine rings lie in a common plane [r.m.s. deviation = 0.023?(2)?Å], whereas the bromo-phenyl and indole rings are twisted away from this plane by 52.82?(12) and 28.02?(10)°, respectively. The crystal structure is stabilized by inter-molecular N-H?N inter-actions.

| S-EPMC2968551 | biostudies-literature

2-Amino-6-(naphthalen-1-yl)-4-phenyl-pyridine-3-carbonitrile.

Project description:In the title compound, C(22)H(15)N(3), the naphthyl ring system makes dihedral angles of 67.40 (2) and 59.80 (3)° with the pyridyl and phenyl rings, respectively. In the crystal, the mol-ecules are connected via inter-molecular N-H⋯N hydrogen bonds, forming a three-dimensional network.

| S-EPMC3099955 | biostudies-literature

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