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[Bis(3-amino-prop-yl)amine-?N,N',N'']bis-(thio-cyanato-?N)cobalt(II).

ABSTRACT: The asymmetric unit of the title compound, [Co(NCS)(2)(C(6)H(17)N(3))], consists of one Co(2+) cation, two thio-cyanate anions and one bis-(3-amino-prop-yl)amine ligand, all in general positions. The cobalt cation is coordinated by five N atoms of two terminal N-bonded thio-cyanate anions and one bis-(3-amino-prop-yl)amine ligand, defining a slightly distorted square-pyramidal coordination polyhedron. The mol-ecules are held together in the crystal by weak N-H?S inter-actions.

SUBMITTER: Boeckmann J 

PROVIDER: S-EPMC3212118 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

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[Bis(3-amino-prop-yl)amine-κN,N',N'']bis-(thio-cyanato-κN)cobalt(II).

Boeckmann Jan J   Näther Christian C  

Acta crystallographica. Section E, Structure reports online 20110706 Pt 8

The asymmetric unit of the title compound, [Co(NCS)(2)(C(6)H(17)N(3))], consists of one Co(2+) cation, two thio-cyanate anions and one bis-(3-amino-prop-yl)amine ligand, all in general positions. The cobalt cation is coordinated by five N atoms of two terminal N-bonded thio-cyanate anions and one bis-(3-amino-prop-yl)amine ligand, defining a slightly distorted square-pyramidal coordination polyhedron. The mol-ecules are held together in the crystal by weak N-H⋯S inter-actions. ...[more]

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