Browse
Submit Data
Databases
API
Help

Dataset Information

27 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Tris(1,10-phenanthroline)cobalt(II) bis-(trichloro-acetate).

ABSTRACT: In the title complex, [Co(C(12)H(8)N(2))(3)](C(2)Cl(3)O(2))(2), the Co(II) ion lies on a twofold rotation axis and is coordinated by six N atoms from three bis-chelating 1,10-phenanthroline ligands in a distorted octa-hedral environment. The crystal structure is stabilized by weak inter-molecular C-H⋯O hydrogen bonds.

SUBMITTER: Li LM

PROVIDER: S-EPMC3152094 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

Tris(1,10-phenanthroline)cobalt(II) bis-(perrhenate) monohydrate.

Project description:In the title compound, [Co(C(12)H(8)N(2))(3)][ReO(4)](2)·H(2)O, the Co(II) atom is coordinated by three 1,10-phenanthroline ligands in a distorted octa-hedral arrangement. In the crystal, the components are linked by O-H?O, C-H?O and aromatic ?-? stacking [shortest centroid-centroid separation = 3.659?(5)?Å] inter-actions.

| S-EPMC3006859 | biostudies-other

Bis(isocyanato-?N)bis-(1,10-phenanthroline-?N,N')cobalt(II).

Project description:In the title complex, [Co(NCO)(2)(C(12)H(8)N(2))(2)], the Co(II) atom, lying on a twofold rotation axis, is coordinated in a distorted octa-hedral environment by four N atoms from two chelating phenanthroline ligands and two N atoms from two isocyanate ligands in cis positions.

| S-EPMC2979601 | biostudies-literature

2,9-Bis(trichloro-meth-yl)-1,10-phenanthroline.

Project description:The asymmetric unit of the title compound, C(14)H(6)Cl(6)N(2), contains two crystallographically independent mol-ecules, each of which is slightly twisted from planarity. The dihedral angles between the central ring and the two outer rings are 3.81?(7) and 4.30?(7)° in one mol-ecule, and 4.13?(8) and 4.10?(7)° in the other. In the crystal structure, mol-ecules are inter-linked by C-Cl?Cl inter-actions into sheets parallel to the ac plane. These sheets are stacked along the b axis in such a way that the mol-ecules are anti-parallel; they are further connected into a supra-molecular network. There are no classical hydrogen bonds. C?Cl [3.637?(2)?Å], Cl?Cl [3.5639?(5)-3.6807?(8)?Å] and Cl?N [3.3802?(15)-3.4093?(15)?Å] short contacts and ?-? inter-actions, with centroid-centroid distances in the range 3.5868?(9)-3.7844?(9)?Å, are observed.

| S-EPMC2979670 | biostudies-literature

Aqua-(hippurato)bis-(1,10-phenanthroline)cobalt(II) nitrate monohydrate.

Project description:In the title compound, [Co(C(9)H(8)NO(3))(C(12)H(8)N(2))(2)(H(2)O)]NO(3)·H(2)O, the Co(II) atom is six-coordinated by a carboxylate O atom of the hippurate (Hc) anion, a water O atom and four N atoms from two 1,10-phenanthroline ligands in a distorted octa-hedral geometry. The uncoordinated O atom of the hippuric acid anion is involved in an intra-molecular hydrogen bond to the coordinated water mol-ecule. The crystal packing is stabilized by inter-molecular O-H?O hydrogen bonds involving the Hc anions, the coordinated water mol-ecule, the nitrate anion and the uncoordinated water mol-ecule.

| S-EPMC3009208 | biostudies-literature

Bis[tris-(1,10-phenanthroline)nickel(II)] tris-[dicyanidoargentate(I)] nitrate 4.2-hydrate.

Project description:The title compound, [Ni(C(12)H(8)N(2))(3)](2)[Ag(CN)(2)](3)(NO(3))·4.2H(2)O, crystallizes with two independent [Ni(phen)(3)](2+) cations (phen is 1,10-phenanthroline; both Ni atoms have threefold symmetry and N(6) donor sets), three near-linear [Ag(CN)(2)](-) anions, one nitrate anion (N site symmetry 3) and 4.2 water mol-ecules of crystallization, some of which are disordered. The [Ag(CN)(2)](-) anions are situated within cavities created by the phenanthroline ligands of adjacent [Ni(phen)(3)](2+) cations. Some short C-H?O and C-H?N inter-actions may help to establish the packing.

| S-EPMC2959559 | biostudies-literature

Di-?-chlorido-bis-[(1,10-phenanthroline-?N,N')(trichloro-acetato-?O)copper(II)].

Project description:The title compound, [Cu(2)(C(2)Cl(3)O(2))(2)Cl(2)(C(12)H(8)N(2))(2)], features a centrosymmetric binuclear complex. The coordination geometry around the Cu(II) atom is square-pyramidal, comprising two N atoms from a symmetrically chelating 1,10-phenanthroline ligand, one O atom from a trichloro-acetate ligand and two Cl(-) anions. In addition, there is a weak intra-molecular Cu?O inter-action of 2.9403?(14)?Å involving the carbonyl O atom of the trichloro-acetate ligand. The central Cu(2)Cl(2) core takes the form of a rhombus, owing to the disparate Cu-Cl bond lengths. Mol-ecules are connected in the crystal structure by C-H?Cl and C-H?O inter-actions.

| S-EPMC3297214 | biostudies-literature

4,7-Diphenyl-2,9-bis-(trichloro-meth-yl)-1,10-phenanthroline.

Project description:In the title compound, C(26)H(14)Cl(6)N(2), the phenanthroline ring system is essentially planar, with an r.m.s. deviation of 0.048?(6)?Å, and makes dihedral angles of 64.8?(14) and 66.6?(6)° with the two terminal phenyl rings. One of the trichloro-methyl groups is disordered over two positions, with occupancies of 0.42?(2) and 0.58?(2).

| S-EPMC2980224 | biostudies-literature

Chloridobis(1,10-phenanthroline-?N,N')(2,2,2-trichloro-acetato-?O)cobalt(II).

Project description:The title compound, [Co(C(2)Cl(3)O(2))Cl(C(12)H(8)N(2))(2)], was obtained by the reaction of trichloro-acetic acid and CoCl(2) in the presence of 1,10-phenanthroline. The Co(II) ion exhibits a distorted octa-hedral geometry, with three N atoms from two 1,10-phenanthroline ligands and the Cl(-) ion in the equatorial plane and one O atom from the trichloro-acetate ligand and one phenanthroline N atom in axial positions. This compound is isostructural with the analogous Mn(II) complex. The trichloro-methyl group of the trichloro-acetate ligand is disordered over two positions with occupancies of 0.190?(5) and 0.810?(5).

| S-EPMC2980258 | biostudies-other

Bis(benzoato-?O,O')(2,9-dimethyl-1,10-phenanthroline-?N,N')cobalt(II).

Project description:In the title compound, [Co(C(7)H(5)O(2))(2)(C(14)H(12)N(2))], the Co(II) ion is located on a twofold rotation axis and is chelated by a 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two benzoate anions in a distorted octa-hedral geometry. The crystal packing is stabilized by ?-? inter-actions between parallel dmphen ligands of neighbouring mol-ecules, with a face-to-face distance of 3.411?(2)?Å.

| S-EPMC2960282 | biostudies-literature

Bis(pentane-2,4-dionato-?O,O')(1,10-phenanthroline-?N,N')cobalt(II).

Project description:In the title compound, [Co(C(5)H(7)O(2))(2)(C(12)H(8)N(2))], the Co(II) cation lies on a twofold rotation axis and is coordinated by four O atoms from two acetyl-acetonate (acac) ligands and two N atoms from a 1,10-phenanthroline (phen) ligand in a slightly distorted octa-hedral environment, with Co-O bond lengths of 2.0565?(11) and 2.0641?(11)?Å and Co-N bond lengths of 2.1630?(12)?Å. In the crystal, there are no significant hydrogen-bonding or ?-? inter-actions.

| S-EPMC3238622 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data