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Poly[[diaqua-deca-?-cyanido-hexa-cyanidobis-(4-cyano-pyridine)di-?-pyrimidine-tricopper(II)ditungsten(V)] dihydrate].


ABSTRACT: In the polymeric title compound, {[Cu(3)W(2)(CN)(16)(C(4)H(4)N(2))(2)(C(6)H(4)N(2))(2)(H(2)O)(2)]·2H(2)O}(n), the coordination geometry of W is an eight-coordinated bicapped trigonal prism. Five of the CN groups of [W(CN)(8)] are bridged to Cu ions. The coordination geometries of the Cu atoms are each pseudo-octa-hedral; one Cu atom is located on a centre of inversion. The cyano-bridged W-Cu layers are linked by Cu-containing pillars, to form a three-dimensional network with cavities occupied by noncoordinated water and 4-cyano-pyridine mol-ecules.

SUBMITTER: Kaneko S 

PROVIDER: S-EPMC2959564 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Poly[[diaqua-deca-μ-cyanido-hexa-cyanidobis-(4-cyano-pyridine)di-μ-pyrimidine-tricopper(II)ditungsten(V)] dihydrate].

Kaneko Souhei S   Tsunobuchi Yoshihide Y   Nakabayashi Koji K   Ohkoshi Shin-Ichi S  

Acta crystallographica. Section E, Structure reports online 20081018 Pt 11


In the polymeric title compound, {[Cu(3)W(2)(CN)(16)(C(4)H(4)N(2))(2)(C(6)H(4)N(2))(2)(H(2)O)(2)]·2H(2)O}(n), the coordination geometry of W is an eight-coordinated bicapped trigonal prism. Five of the CN groups of [W(CN)(8)] are bridged to Cu ions. The coordination geometries of the Cu atoms are each pseudo-octa-hedral; one Cu atom is located on a centre of inversion. The cyano-bridged W-Cu layers are linked by Cu-containing pillars, to form a three-dimensional network with cavities occupied by  ...[more]

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