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Poly[bis[3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexa-azacyclo-tetra-deca-ne]tetra-μ-cyanido-tetracyanidodicopper(II)molybdenum(IV)] tetra-hydrate].

ABSTRACT: In the title complex, {[Cu(2)Mo(CN)(8)(C(12)H(30)N(6)O(2))(2)]·4H(2)O}(n), the polyhedron around Mo has site symmetry with a distorted square-antiprismatic shape, while the Cu atom (2 symmetry) is in a distorted axially elongated octa-hedral coordination environment. The uncoordinated water molecule is disordered over three sites with occupancies of 0.445 (7), 0.340 (7) and 0.215 (7). Mo and Cu atoms acting as basic components are connected by an Mo-CN-Cu-NC-Mo- linkage to form a distorted diamond-like network. Additional hydrogen bonding between the N-H groups and the water molecules stabilizes this arrangement.

SUBMITTER: Zhou H

PROVIDER: S-EPMC2959912 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Poly[bis[3,10-bis(2-hydroxyethyl)-1,3,5,8,10,12-hexa-azacyclo-tetra-deca-ne]tetra-μ-cyanido-tetracyanidodicopper(II)molybdenum(IV)] tetra-hydrate].

Zhou Hu H Chen Ying-Ying YY Liu Wen-Yan WY Yuan Ai-Hua AH

Acta crystallographica. Section E, Structure reports online 20081113 Pt 12

In the title complex, {[Cu(2)Mo(CN)(8)(C(12)H(30)N(6)O(2))(2)]·4H(2)O}(n), the polyhedron around Mo has site symmetry with a distorted square-antiprismatic shape, while the Cu atom (2 symmetry) is in a distorted axially elongated octa-hedral coordination environment. The uncoordinated water molecule is disordered over three sites with occupancies of 0.445 (7), 0.340 (7) and 0.215 (7). Mo and Cu atoms acting as basic components are connected by an Mo-CN-Cu-NC-Mo- linkage to form a distorted diamo ...[more]

PMID: 21581144

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