Ontology highlight
ABSTRACT:
SUBMITTER: Berends T
PROVIDER: S-EPMC2979617 | biostudies-literature | 2010 May
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20100529 Pt 6
In the title 2:1 adduct, [Sn(2)W(2)(C(10)H(13)NO(2))(2)(CO)(10)](2)[W(CO)(6)], the complete hexa-carbonyl-tungsten mol-ecule is generated by a crystallographic inversion centre. The heterometallic mol-ecule features a central Sn(2)O(2) core with essentially equal Sn-O(eth-oxy) bond lengths. The second eth-oxy O and amine N atoms of each N,O,O'-tridentate ligand coordinate to one Sn atom only. The NO(3) donor atoms occupy basal positions and the W atom the apical position in a distorted square-py ...[more]