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Bis{4-chloro-6-formyl-2-[(E)-2-(1H-imidazol-4-yl-?N)ethyl-imino-methyl-?N]phenolato-?O}nickel(II).

ABSTRACT: In the title compound, [Ni(C(13)H(11)ClN(3)O(2))(2)], the Ni(II) atom is located on a twofold rotation axis and is six-coordinated by four N atoms and two phenolate O atoms from the two equal Schiff base ligands in a distorted octa-hedral coordination geometry. The complex mol-ecules are connected by C-H?Cl, C-H?O and N-H?O hydrogen bonds.

SUBMITTER: Mao JW

PROVIDER: S-EPMC2959577 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Bis{4-chloro-6-formyl-2-[(E)-2-(1H-imidazol-4-yl-κN)ethyl-imino-methyl-κN]phenolato-κO}nickel(II).

Mao Jia-Wei JW Zhou Hong H Pan Zhi-Quan ZQ Meng Xiang-Gao XG

Acta crystallographica. Section E, Structure reports online 20081004 Pt 11

In the title compound, [Ni(C(13)H(11)ClN(3)O(2))(2)], the Ni(II) atom is located on a twofold rotation axis and is six-coordinated by four N atoms and two phenolate O atoms from the two equal Schiff base ligands in a distorted octa-hedral coordination geometry. The complex mol-ecules are connected by C-H⋯Cl, C-H⋯O and N-H⋯O hydrogen bonds. ...[more]

PMID: 21580826

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