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Bis{2-[2-(1H-indol-3-yl)ethyl-imino-meth-yl]phenolato-?N,O}nickel(II) N,N-dimethyl-formamide disolvate.

ABSTRACT: The Ni atom in the title compound, [Ni(C(17)H(15)N(2)O)(2)]·2C(3)H(7)NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyl-imino-meth-yl]phenolate ligand in a square-planar coordination environment. The mol-ecule is linked to a solvent mol-ecule by an indole-dimethyl-formamide N-H?O hydrogen bond.

SUBMITTER: Ali HM

PROVIDER: S-EPMC2961391 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Bis{2-[2-(1H-indol-3-yl)ethyl-imino-meth-yl]phenolato-κN,O}nickel(II) N,N-dimethyl-formamide disolvate.

Ali Hapipah M HM Mohamed Mustafa Mohamed Ibrahim MI Rizal Mohd Razali MR Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20080510 Pt 6

The Ni atom in the title compound, [Ni(C(17)H(15)N(2)O)(2)]·2C(3)H(7)NO, lies on a twofold rotation axis. It is N,O-chelated by the deprotonated Schiff base 2-[2-(1H-indol-3-yl)ethyl-imino-meth-yl]phenolate ligand in a square-planar coordination environment. The mol-ecule is linked to a solvent mol-ecule by an indole-dimethyl-formamide N-H⋯O hydrogen bond. ...[more]

PMID: 21202476

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Bis{2-(5-hydr-oxy-2-[1-(hydroxy-imino)eth-yl]phenolato-?O,N}nickel(II) N,N-dimethyl-formamide disolvate.

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