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Rac-Carbon-yl{1-[(diphenyl-phosphino)meth-yl]ethanethiol-ato}(triphenyl-phosphine)rhodium(I).

ABSTRACT: The title compound, [Rh(C(15)H(16)PS)(C(18)H(15)P)(CO)], was synthesized from the reaction of the ligand rac-[Ph(2)PCH(2)CH(CH(3))SH] with trans-[Rh(F)(CO)(PPh(3))(2)] in a 1:1 molar ratio in toluene. The Rh atom is four-coordinated in a distorted square-planar geometry with the P-S ligand [Ph(2)PCH(2)CH(CH(3))S] acting as a chelate and the PPh(3) and disordered CO [site occupation factors of 0.61?(5) and 0.39?(5)] ligands completing the coordination.

SUBMITTER: Hernandez-Ortega S

PROVIDER: S-EPMC2959607 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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rac-Carbon-yl{1-[(diphenyl-phosphino)meth-yl]ethanethiol-ato}(triphenyl-phosphine)rhodium(I).

Hernández-Ortega Simón S Morales-Morales David D

Acta crystallographica. Section E, Structure reports online 20081025 Pt 11

The title compound, [Rh(C(15)H(16)PS)(C(18)H(15)P)(CO)], was synthesized from the reaction of the ligand rac-[Ph(2)PCH(2)CH(CH(3))SH] with trans-[Rh(F)(CO)(PPh(3))(2)] in a 1:1 molar ratio in toluene. The Rh atom is four-coordinated in a distorted square-planar geometry with the P-S ligand [Ph(2)PCH(2)CH(CH(3))S] acting as a chelate and the PPh(3) and disordered CO [site occupation factors of 0.61 (5) and 0.39 (5)] ligands completing the coordination. ...[more]

PMID: 21580902

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