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[(Di-o-tolyl-phosphino)meth-yl]diphenyl-phosphine sulfide.

ABSTRACT: In the title compound, C(27)H(26)P(2)S, the P-C-P angle is 114.33?(13)°. The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons. One phenyl ring is disordered over three sites [occupancies 0.317?(8), 0.250?(8), and 0.433?(6)] and the other phenyl ring is disordered over two sites [occupancies 0.871?(6) and 0.129?(6)].

SUBMITTER: Pitroda PP

PROVIDER: S-EPMC2970358 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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[(Di-o-tolyl-phosphino)meth-yl]diphenyl-phosphine sulfide.

Pitroda Priyanka P PP Badgett Ansonia H AH Dickey Geralyn A GA Gray Danielle L DL Shelby Quinetta D QD

Acta crystallographica. Section E, Structure reports online 20090905 Pt 10

In the title compound, C(27)H(26)P(2)S, the P-C-P angle is 114.33 (13)°. The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons. One phenyl ring is disordered over three sites [occupancies 0.317 (8), 0.250 (8), and 0.433 (6)] and the other phenyl ring is disordered over two sites [occupancies 0.871 (6) and 0.129 (6)]. ...[more]

PMID: 21577779

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