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Catena-Poly[[{2-meth-oxy-6-[(4-methyl-phen-yl)imino-meth-yl]phenolato}-cad-mium(II)]-di-?(2)-chlorido-[dimethanol-cadmium(II)]-di-?(2)-chlorido-[{2-meth-oxy-6-[(4-methyl-phen-yl)imino-meth-yl]-phenolato}cadmium(II)]-di-?(2)-chlorido].

ABSTRACT: The structure of the title compound, [Cd(3)Cl(6)(C(15)H(15)NO(2))(2)(CH(4)O)(2)](n), is based on a layered zigzag polymeric chain along the c axis. The Cd(II) ions are linked by double chlorine bridges alternating between one CdCl(4)(CH(3)OH)(2) and two CdCl(4)(C(15)H(15)NO(2)) octa-hedral coordination units. Additional intrachain N-H?O and O-H?Cl hydrogen-bond interactions stabilize this arrangement.

SUBMITTER: Xian HD

PROVIDER: S-EPMC2959620 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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catena-Poly[[{2-meth-oxy-6-[(4-methyl-phen-yl)imino-meth-yl]phenolato}-cad-mium(II)]-di-μ(2)-chlorido-[dimethanol-cadmium(II)]-di-μ(2)-chlorido-[{2-meth-oxy-6-[(4-methyl-phen-yl)imino-meth-yl]-phenolato}cadmium(II)]-di-μ(2)-chlorido].

Xian Hui-Duo HD Li Hua-Qiong HQ Liu Jian-Feng JF Zhao Guo-Liang GL

Acta crystallographica. Section E, Structure reports online 20081018 Pt 11

The structure of the title compound, [Cd(3)Cl(6)(C(15)H(15)NO(2))(2)(CH(4)O)(2)](n), is based on a layered zigzag polymeric chain along the c axis. The Cd(II) ions are linked by double chlorine bridges alternating between one CdCl(4)(CH(3)OH)(2) and two CdCl(4)(C(15)H(15)NO(2)) octa-hedral coordination units. Additional intrachain N-H⋯O and O-H⋯Cl hydrogen-bond interactions stabilize this arrangement. ...[more]

PMID: 21580884

Similar Datasets

Crystal structure of di-chlorido-bis-{μ-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}{2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}cadmium(II)cobalt(III) monohydrate.

Project description:The title compound, [CoCd(C9H10NO2)3Cl2]·H2O, is a solvatomorph of the corresponding hemihydrate recently published by us [Nesterova et al. (2018 ▸). Appl. Cat. A, 560, 171-184]. The current structure reveals different cell parameters and space group compared with the published one while both are monoclinic with almost the same cell volume. The title compound is formed of discrete neutral dinuclear mol-ecules with no crystallographically imposed symmetry and water mol-ecules of crystallization. The overall geometry about the cobalt(III) ion is octa-hedral with an N3O3 environment; each ligand acts as a meridional ONO donor. The CdII coordination sphere approximates an irregular square pyramid with a chlorine atom at the apex. There is significant shortening of a Cd-O bond length to the oxygen atom of the methoxo group on one of the ligands [2.459 (3) Å] compared to the corresponding distance in the published structure [2.724 (7) Å], while other Cd-Cl/N/O bonds remain roughly the same. In the crystal lattice, the heterometallic mol-ecules, which are related by the crystallographic n-glide plane and inter-linked by weak hydrogen bonds to solvent water mol-ecules, form columns along [101]. Adjacent columns lie anti-parallel to each other.

| S-EPMC6218914 | biostudies-literature

Bis{?-2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}bis-({2-meth-oxy-6-[(methyl-imino)-meth-yl]phenolato}copper(II)).

Project description:The title compound, [Cu2(C9H10NO2)4], is built of discrete centrosymmetric dimers. The Cu(II) atoms are each five coordinated by two deprotonated Schiff base ligands that are bonded differently to the metal atoms. Of the two phenolate O atoms, one is coordinated to one Cu(II) atom, whereas another bridges the two metal atoms. The basal plane of the square pyramid around Cu(II) atoms is formed by the imino N and phenolate O atoms of the bidentate and the monodentate/bidentate Schiff base ligands. The bridging phenolate oxygen occupies the apical position of the coordination sphere with a considerably longer Cu-O bond length. In the crystal, the dimeric mol-ecules pack relative to each other in such a way that the Cu2O2 planes of adjacent dimers are orthogonal.

| S-EPMC3790358 | biostudies-literature

Bis{2-[imino-(phen-yl)meth-yl]-5-meth-oxy-phenolato-?(2)N,O(1)}nickel(II).

Project description:The title complex, [Ni(C(14)H(12)NO(2))(2)], lies about an inversion center. The Ni(II) atom is coordinated in a slightly distorted square-planar geometry by two O atoms and two N atoms from two 2-[imino-(phen-yl)meth-yl]-5-meth-oxy-phenolate ligands. The dihedral angle between the symmetry-unique phenyl and benzene rings is 73.2?(1)°.

| S-EPMC3515134 | biostudies-literature

Di-?-chlorido-bis-({9-[(2,6-diisopropyl-phen-yl)imino-meth-yl]anthracen-1-yl}palladium(II)).

Project description:The centrosymmetric title compound, [Pd(2)Cl(2)(C(27)H(26)N)(2)], was obtained by a C-H bond-activation reaction of a Schiff base ligand with Li(2)PdCl(4) in methanol, and was crystallized from dichloro-methane as orange crystals. The Pd atom displays a slightly distorted square-planar geometry, with the N- and C-atom donors in a cis arrangement.

| S-EPMC2961217 | biostudies-literature

Di-μ-chlorido-bis-(chlorido{2-[(4-ethyl-phen-yl)imino-meth-yl]pyridine-κN,N'}copper(II)).

Project description:The binuclear title complex, [Cu(2)Cl(4)(C(14)H(14)N(2))(2)], is located on a crystallographic inversion centre. The Cu(II) ion is in a distorted square-pyramid coordination environment formed by the bichelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Cu-Cl bonds is significantly longer than the other.

| S-EPMC3200970 | biostudies-literature

Di-?-chlorido-bis-({2-[(4-bromo-phen-yl)-imino-meth-yl]pyridine-?N,N'}-chloridomercury(II)).

Project description:The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal-bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.

| S-EPMC2977257 | biostudies-literature

Di-μ-chlorido-bis-[(2-{(E)-[(2,3-dihy-droxy-prop-yl)imino]-meth-yl}phenolato)copper(II)] methanol monosolvate.

Project description:In the title compound, [Cu(2)Cl(2)(C(10)H(12)NO(3))(2)]·CH(3)OH, each of the two Cu(II) atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands. The metal atoms each show a distorted square-pyramidal coordination geometry. Intra-molecular O-H⋯O hydrogen bonds occur. In the crystal, O-H⋯O hydrogen bonds join the components into a chain extending along the a axis.

| S-EPMC3246963 | biostudies-literature

Bis{2-[(2-cyano-phen-yl)imino-meth-yl]phenolato}copper(II).

Project description:In the title mononuclear copper(II) complex, [Cu(C(14)H(9)N(2)O)(2)], the Cu(II) atom, situated on an inversion centre, shows a slightly distorted square-planar geometry and is coordinated by the N and O atoms from two deprotonated symmetry-related Schiff base ligands. The Cu-N and Cu-O bond lengths are 2.009 (2) and 1.888 (2) Å, respectively. The dihedral angle between the cyano-phenyl rings and phenolate rings is 42.28 (13)°.

| S-EPMC2959947 | biostudies-literature

Chlorido[2-meth-oxy-6-(2-pyridyl-methyl-imino-meth-yl)phenolato]zinc(II).

Project description:In the title mol-ecule, [Zn(C(14)H(13)N(2)O(2))Cl], the Zn(II) ion is coordinated by one O and two N atoms from the Schiff base ligand, and a chloride anion in a distorted square-planar geometry. In the crystal structure, ?-? inter-actions link the approximately planar (mean deviation 0.0569?Å) mol-ecules into stacks parallel to the a axis.

| S-EPMC2971112 | biostudies-other

Bis(6-meth-oxy-2-{[tris-(hydroxy-meth-yl)-meth-yl]-imino-meth-yl}phenolato)-copper(II) dihydrate.

Project description:In the title compound, [Cu(C(12)H(16)NO(5))(2)]·2H(2)O, the Cu(II) ion adopts a trans-CuN(2)O(4) octa-hedral geometry arising from two N,O,O'-tridentate 6-meth-oxy-2-{[tris-(hydroxy-meth-yl)meth-yl]-imino-meth-yl}phenolate ligands. The Jahn-Teller distortion of the copper centre is unusally small. In the crystal structure, O-H?O hydrogen bonds, some of which are bifurcated, link the component species.

| S-EPMC2968260 | biostudies-literature

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