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Di-μ-chlorido-bis-[(2-{(E)-[(2,3-dihy-droxy-prop-yl)imino]-meth-yl}phenolato)copper(II)] methanol monosolvate.

ABSTRACT: In the title compound, [Cu(2)Cl(2)(C(10)H(12)NO(3))(2)]·CH(3)OH, each of the two Cu(II) atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands. The metal atoms each show a distorted square-pyramidal coordination geometry. Intra-molecular O-H⋯O hydrogen bonds occur. In the crystal, O-H⋯O hydrogen bonds join the components into a chain extending along the a axis.

SUBMITTER: Li Y

PROVIDER: S-EPMC3246963 | biostudies-literature | 2011 Nov

REPOSITORIES: biostudies-literature

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Di-μ-chlorido-bis-[(2-{(E)-[(2,3-dihy-droxy-prop-yl)imino]-meth-yl}phenolato)copper(II)] methanol monosolvate.

Li Yong Y

Acta crystallographica. Section E, Structure reports online 20111012 Pt 11

In the title compound, [Cu(2)Cl(2)(C(10)H(12)NO(3))(2)]·CH(3)OH, each of the two Cu(II) atoms is bound to two O and one N atoms of the bis-chelating monoanionic Schiff base and two bridging chloride ligands. The metal atoms each show a distorted square-pyramidal coordination geometry. Intra-molecular O-H⋯O hydrogen bonds occur. In the crystal, O-H⋯O hydrogen bonds join the components into a chain extending along the a axis. ...[more]

PMID: 22219783

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