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Bis(4-amino-benzoato-?O)triphenylanti-mony(V).

ABSTRACT: The structure of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], contains two independent mol-ecules of similar configuration. The Sb atoms exhibit a distorted trigonal-bipyramidal geometry with the O atoms of two carboxyl-ate groups in the axial positions and the C atoms of the phenyl groups in the equatorial positions. In the crystal structure, mol-ecules are connected by inter-molecular N-H?O and N-H?N hydrogen-bonding inter-actions forming a chain structure along [100].

SUBMITTER: Wen L

PROVIDER: S-EPMC2959708 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Bis(4-amino-benzoato-κO)triphenylanti-mony(V).

Wen Liyuan L Yin Handong H Wang Daqi D Cui Liansheng L Yang Minglei M

Acta crystallographica. Section E, Structure reports online 20081018 Pt 11

The structure of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], contains two independent mol-ecules of similar configuration. The Sb atoms exhibit a distorted trigonal-bipyramidal geometry with the O atoms of two carboxyl-ate groups in the axial positions and the C atoms of the phenyl groups in the equatorial positions. In the crystal structure, mol-ecules are connected by inter-molecular N-H⋯O and N-H⋯N hydrogen-bonding inter-actions forming a chain structure along [100]. ...[more]

PMID: 21580870

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