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Bis(5-amino-2-chloro-benzoato-?O)triphenyl-anti-mony(V).

ABSTRACT: In the title compound, [Sb(C(6)H(5))(3)(C(7)H(5)ClNO(2))(2)], the Sb center has a distorted trigonal-bipyramidal geometry, with the O atoms of two carboxyl-ate groups in axial positions and the C atoms of the phenyl groups in equatorial positions. Intra-molecular C-H?O inter-actions occur. The mol-ecules are connected by inter-molecular N-H?O, N-H?N and C-H?O hydrogen-bonding inter-actions and C-H?? stacking inter-actions, forming a three-dimensional supra-molecular framework.

SUBMITTER: Wen L

PROVIDER: S-EPMC2971366 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Bis(5-amino-2-chloro-benzoato-κO)triphenyl-anti-mony(V).

Wen Liyuan L Yin Handong H Wang Chuanhua C

Acta crystallographica. Section E, Structure reports online 20091028 Pt 11

In the title compound, [Sb(C(6)H(5))(3)(C(7)H(5)ClNO(2))(2)], the Sb center has a distorted trigonal-bipyramidal geometry, with the O atoms of two carboxyl-ate groups in axial positions and the C atoms of the phenyl groups in equatorial positions. Intra-molecular C-H⋯O inter-actions occur. The mol-ecules are connected by inter-molecular N-H⋯O, N-H⋯N and C-H⋯O hydrogen-bonding inter-actions and C-H⋯π stacking inter-actions, forming a three-dimensional supra-molecular framework. ...[more]

PMID: 21578174

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