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Bis(2,4-dichloro-phen-oxy-acetato-?O,O)(5,5'-dimethyl-2,2'-bipyridine-?N,N')cobalt(II).

ABSTRACT: In the title compound, [Co(C(8)H(5)Cl(2)O(3))(C(12)H(12)N(2))], the Co(II) atom, lying on a twofold rotation axis, is coordinated by four O atoms from two chelating 2,4-dichloro-phen-oxy-acetate ligands and two N atoms from a 5,5'-dimethyl-2,2'-bipyridine ligand, displaying a distorted octa-hedral geometry. A three-dimensional supra-molecular structure is formed through inter-molecular C-H?O hydrogen bonds and ?-? stacking inter-actions between the pyridine and benzene rings [centroid-centroid distance = 3.779?(2)?Å].

SUBMITTER: Ji LL 

PROVIDER: S-EPMC3099758 | biostudies-literature | 2011 Apr

REPOSITORIES: biostudies-literature

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Bis(2,4-dichloro-phen-oxy-acetato-κO,O)(5,5'-dimethyl-2,2'-bipyridine-κN,N')cobalt(II).

Ji Li-Li LL   Liu Jian-She JS   Song Wen-Dong WD  

Acta crystallographica. Section E, Structure reports online 20110326 Pt 4

In the title compound, [Co(C(8)H(5)Cl(2)O(3))(C(12)H(12)N(2))], the Co(II) atom, lying on a twofold rotation axis, is coordinated by four O atoms from two chelating 2,4-dichloro-phen-oxy-acetate ligands and two N atoms from a 5,5'-dimethyl-2,2'-bipyridine ligand, displaying a distorted octa-hedral geometry. A three-dimensional supra-molecular structure is formed through inter-molecular C-H⋯O hydrogen bonds and π-π stacking inter-actions between the pyridine and benzene rings [centroid-centroid d  ...[more]

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